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Topic: Spontaneity in REDOX
DO NOW: One beaker Contains: Zn(NO3)2 & Cu AgNO3 & Cu Which beaker is which…how can you tell?!
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Single Replacement reactions are Redox Rxns
Use table J to predict if the reaction is spontaneous Any metal will donate (lose) its electrons to ion of any metal below it. = Spontaneous Any nonmetal will steal (gain) electrons from the ion of any nonmetal below it. = Spontaneous
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One beaker Contains: Zn(NO3)2 & Cu AgNO3 & Cu Which beaker is which…how can you tell?!
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Which of the following will occur spontaneously
Li + AlCl3 Cs + CuCl2 I2 + NaCl Cl2 + KBr Fe + CaBr2 Mg + Sr(NO3)2 F2 + MgCl2 Yes Yes No Yes No No Yes
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If the metal being oxidized is higher on table J, the rxn is spontaneous
You just told me this is spontaneous 3Li + AlCl3 3LiCl + Al Let’s look at it in terms of Oxidation Reduction Lithium = 0 +3 so it was oxidized Aluminum = +30 so it was reduced
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If the nonmetal being reduced is higher on table J, the rxn is spontaneous
You just told me this is spontaneous F2 + MgCl2 MgF2 + Cl2 Let’s look at it in terms of Oxidation Reduction Fluorine = 0 -1 so it was reduced Chlorine = -10 so it was oxidized
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Let’s try p. 9, cross out 4-6
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