1. HBr
Relevant to the HBr-FvsV state paper:

2. Model: 1/t0E1 E1 1/tE1 1/t0H0 H0 1/tF1 1/t0F1 V7 F1 1/tH0 1/tother
Assume:

3. Linewidths

4. Bw vs lifetime comparisons79
J´=6
J´=3
states:
Bw/cm-1
t(ps)=
1/t (ps-1)
rate const. Sums
fraction V7
ca. 1 ? E1
> F1
1.4125
>> H0
E1+F1+H0
diff/others:
J´=5(?)
J´=4 8
guess!
0.6625
7.6149

5. Bw vs lifetime comparisons81
J´=6
J´=3
states:
Bw/cm-1
t(ps)=
1/t (ps-1)
rate const. Sums
fraction V7
ca. 1 ? E1
> F1
>> H0
E1+F1+H0
diff/others:
J´=5(?)
J´=4
8.525
guess!
7.6149

6. In summary: according to J´=4 and 6: i = 79 & 81 : rates ca.
1/tV7 = 1.47 ps-1
1/t0E1 E1
1/tE1 =
0.83 ps-1
1/t0H0
1/tF1 =0.27 H0
1/t0F1
1/tH0
=0.23 ps-1 V7 F1
1/tother
=0.11 ps-1

7. In summary: according to J´=4 and 6: i = 79& 81 : fractional rates ca
Rel. 1/tV7 = 1
1/t0E1 E1
Rel. 1/tE1 =
0.58
Rel.
1/tF1 =0.19
1/t0H0 H0
1/t0F1
Rel. 1/tH0
=0.16 V7 F1
1/tother
=0.07