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Carboxylic acids AH Chemistry, Unit 3(b).

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Presentation on theme: "Carboxylic acids AH Chemistry, Unit 3(b)."— Presentation transcript:

1 Carboxylic acids AH Chemistry, Unit 3(b)

2 Functional group

3 Dimers Causes relatively high boiling points.
But do not exist in aqueous solution.

4 Properties Solubility How does this compare to alcohols? Why?

5 The carbonyl group has electron withdrawing properties and makes the O-H bond even more polar.

6 Properties pH in aqueous solution

7 The stability of the carboxylate ion is stabilised by electron delocalisation.
So less likely to recombine with H+

8 Preparation Oxidation of aldehydes
Hydrolysis of esters, amides or nitriles

9 Reactions Neutralisation with bases and metals
Producing salts Condensation with alcohols Producing esters Reaction with ammonia Producing ammonium salts, then amides Reduction with lithium aluminium hydride Producing primary alcohols


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