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Carboxylic acids AH Chemistry, Unit 3(b)
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Functional group
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Dimers Causes relatively high boiling points.
But do not exist in aqueous solution.
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Properties Solubility How does this compare to alcohols? Why?
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The carbonyl group has electron withdrawing properties and makes the O-H bond even more polar.
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Properties pH in aqueous solution
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The stability of the carboxylate ion is stabilised by electron delocalisation.
So less likely to recombine with H+
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Preparation Oxidation of aldehydes
Hydrolysis of esters, amides or nitriles
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Reactions Neutralisation with bases and metals
Producing salts Condensation with alcohols Producing esters Reaction with ammonia Producing ammonium salts, then amides Reduction with lithium aluminium hydride Producing primary alcohols
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