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Safety Data Sheets Formerly MSDS
Required by OSHA in the Hazard Communication Standard (HCS) – not effective until June 1, 2015 Standardized sections (compared to MSDS) – 16 of them Used to communicate hazards
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Major Changes/Impact of GHS
> Section 2 of the SDS 9 pictograms that visually describe hazards 2 signal words (danger and warning) that describe the hazards 72 individual and 17 combined precautionary statements
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Pictograms Click here for a handout of the GHS Pictograms
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Signal Words Two signal words; used to indicate the relative level of severity of the hazard: Danger Warning Danger indicates a more serious hazard than warning
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Hazard/precautionary statements
Click here to see how signal words, pictograms, hazard statements, and precautionary statements come together for each hazard class
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SDS Section Titles Identification Hazard(s) identification
Composition/information on ingredients First-aid measures Fire-fighting measures Accidental release measures Handling and storage Identification: includes product identifies, manufacturer or distributor name, address, phone number, emergency phone number, recommended use, and restrictions on use Hazard(s) identification: includes all hazards regarding the chemical, required label elements Composition/information on ingredients: includes information on chemical ingredients; trade secret claims First aid measures: includes important symptoms/effects, acute, delayed; required treatment Accidental release measures: lists emergency procedures; protective equipment; proper methods of containment and cleanup Handling and storage: lists precautions for safe handling and storage, including incompatibilities
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SDS Section Titles Exposure controls/personal protection
Physical and chemical properties Stability and reactivity Toxicological information Ecological information Disposal considerations Transport information Regulatory information Other information Exposure controls/personal protection: lists OSHAs permissible exposure limits (PELs); Threshold limit values (TLVs); appropriate engineering controls; personal protective equipment (PPE) Toxicological information: includes routes of exposure; related symptoms, acute and chronic effects; numerical measures of toxicity
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The Major Change in SDSs
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The Major Change in SDSs
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The Major Change in SDSs
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The Major Change in SDSs
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Who is responsible for reviewing SDS?
Anyone using a material should review the SDS first Supervisors are responsible for ensuring that employees have access to SDS If there is an accident involving an exposure to a hazardous materials, take a copy of the SDS to the health care provider
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For additional SDS information
UC Denver EHS website on SDS SDS Hyperglossary — A search site by Interactive Learning Paradigms, inc. SDS-SEARCH — A fairly comprehensive compilation of SDS databases. Includes some listed below. Fisher Scientific — SDS information is available from Fisher by clicking on the Safety Information button at the end of the catalogue listing for a particular chemical substance. Sigma Aldrich — Sigma Aldrich Safety Data Sheets are now available on line. You should register ahead of time for quicker access. VWR Scientific - SDS sheets for VWR chemicals. Vermont Safety Information Resources on the Internet (SIRI)
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