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CH. 2 - MEASUREMENT I. Using Measurements
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A. Accuracy vs. Precision
Accuracy - how close a measurement is to the accepted value Precision - how close a series of measurements are to each other ACCURATE = CORRECT PRECISE = CONSISTENT
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B. Percent Error Indicates accuracy of a measurement your value
accepted value
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B. Percent Error % error = 2.9 %
A student determines the density of a substance to be 1.40 g/mL. Find the % error if the accepted value of the density is 1.36 g/mL. % error = 2.9 %
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C. Significant Figures Indicate precision of a measurement.
Recording Sig Figs Sig figs in a measurement include the known digits plus a final estimated digit 2.35 cm
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C. Significant Figures Counting Sig Figs (Table 2-5, p.47)
Count all numbers EXCEPT: Leading zeros Trailing zeros without a decimal point -- 2,500
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Counting Sig Fig Examples
C. Significant Figures Counting Sig Fig Examples 4 sig figs 3 sig figs 3. 5,280 3. 5,280 3 sig figs 2 sig figs
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C. Significant Figures (13.91g/cm3)(23.3cm3) = 324.103g 324 g
Calculating with Sig Figs Multiply/Divide - The # with the fewest sig figs determines the # of sig figs in the answer. (13.91g/cm3)(23.3cm3) = g 4 SF 3 SF 3 SF 324 g
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C. Significant Figures 3.75 mL + 4.1 mL 7.85 mL 3.75 mL + 4.1 mL
Calculating with Sig Figs (con’t) Add/Subtract - The # with the lowest decimal value determines the place of the last sig fig in the answer. 3.75 mL mL 7.85 mL 3.75 mL mL 7.85 mL 224 g + 130 g 354 g 224 g + 130 g 354 g 7.9 mL 350 g
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C. Significant Figures Calculating with Sig Figs (con’t)
Exact Numbers do not limit the # of sig figs in the answer. Counting numbers: 12 students Exact conversions: 1 m = 100 cm “1” in any conversion: 1 in = 2.54 cm
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C. Significant Figures Practice Problems 5. (15.30 g) ÷ (6.4 mL)
4 SF 2 SF = g/mL 2.4 g/mL 2 SF g g 18.1 g 18.06 g
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D. Scientific Notation 65,000 kg 6.5 × 104 kg
Converting into Sci. Notation: Move decimal until there’s 1 digit to its left. Places moved = exponent. Large # (>1) positive exponent Small # (<1) negative exponent Only include sig figs.
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D. Scientific Notation Practice Problems 7. 2,400,000 g 8. 0.00256 kg
9. 7 10-5 km 104 mm 2.4 106 g 2.56 10-3 kg km 62,000 mm
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D. Scientific Notation Calculating with Sci. Notation
(5.44 × 107 g) ÷ (8.1 × 104 mol) = Type on your calculator: EXP EE EXP EE ENTER EXE 5.44 7 8.1 ÷ 4 = = 670 g/mol = 6.7 × 102 g/mol
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E. Proportions Direct Proportion y x Inverse Proportion y x
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