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Dipole Forces Main Concept:
Dipole forces result from the attraction among the positive ends and negative ends of polar molecules. Hydrogen bonding is a strong type of dipole-dipole force that exists when very electronegative atoms (N, O, and F) are involved.
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Dipole Forces Dipoles Definition Causes
Polar vs. Nonpolar Interactions Types of Dipoles Dipole-Dipole Dipole-Induced Dipole Hydrogen Bonding Definition Causes
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- Dipole: an atom or molecule which has slight negative and positive ends caused by an uneven distribution of electrons - Electronegativity differences are responsible for uneven distributions of electrons between atoms
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vs - Molecules with dipole moments experience Coulombic interactions resulting in net attractive interaction when near each other Intermolecular dipole-dipole forces are weaker than ionic forces/covalent bonds Interactions between polar molecules are typically greater than between nonpolar molecules of comparable size because interactions act in addition to London dispersion forces
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(from previous) Dipole-dipole attractions represented by diagrams showing positive and negative ends of polar molecules maximizing attractions and minimizing repulsions as a liquid or solid Dipole-induced dipole interactions between polar and nonpolar molecules; strength of these forces increases with magnitude of dipole of polar molecule and with polarizability of nonpolar molecule
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Question: Order the following in terms of which would have a greater magnitude of dipole and explain why you think this. HF vs H2O vs NH3
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- Hydrogen bonding a relatively strong type of intermolecular interaction
- Between hydrogen atoms covalently bonded to highly electronegative atoms (N, O, and F) attracted to negative ends of a dipole formed by electronegative atoms (N, O, and F) in a different molecule, or different part of same molecule - When hydrogen bonding is present, small molecules may have strong intermolecular attractions
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- Representations of hydrogen bonding b/w molecules, or b/w different parts of single molecule (DNA, proteins), show diagrams of molecules with hydrogen bonding and location of hydrogen bonds
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- Ionic interactions with dipoles are important in solubility of ionic compounds in polar solvents
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