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8.3 – Strong vs. Weak Acid & Base Titrations
Topic 8 – Acids & Bases 8.3 – Strong vs. Weak Acid & Base Titrations
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Strong and Weak Acids and Bases
Objectives: Understand the difference between strong and weak acids and bases Complete an experiment to explore the difference in properties of strong/weak acids and bases
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Strong and Weak Acids Strong Acids:
HA(aq) H+(aq) + A ̶ (aq) …..the acid fully dissociates into ions For example: HCl(aq) H+(aq) + Cl ̶ (aq) Includes: hydrochloric, sulfuric, phosphoric, nitric Strong acids have weak conjugate bases Weak Acids: HA(aq) H+(aq) + A ̶ (aq) …..the acid only partially dissociates into ions For example: HF(aq) H+(aq) + F ̶ (aq) Includes: hydrofluoric, ethanoic, carbonic Weak acids have strong conjugate bases
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Strong and Weak Bases Strong Bases:
BOH(aq) B+(aq) + OH ̶ (aq) …..the base fully dissociates into ions For example: NaOH(aq) Na+(aq) + OH ̶ (aq) Includes: group (I) hydroxides, barium hydroxide Strong bases have weak conjugate acids Weak Bases: BOH(aq) B+(aq) + OH ̶ (aq) …..the base only partially dissociates into ions For example: NH3(aq) + H2O(l) NH4+(aq) + OH ̶ (aq) Includes: ammonia, amines Weak bases have strong conjugate acids
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So what? The equilibrium has a profound effect on the properties of the acid/base Compared with strong acids of the same concentration, weak acids: Have lower electrical conductivity React more slowly pH is higher (less acid) Change pH more slowly when diluted However, they neutralise the same volume of alkali Weak bases follow a similar pattern
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Strong Acid & Strong Base
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Strong Acid & Weak Base
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Weak Acid & Strong Base
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Weak Acid & Weak Base
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Compare Titration Curves
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Simulation solutions
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Key Points Strong acids/bases dissociate fully into ions
Weak acids/bases only partially dissociate, forming an equilibrium The strong/weak character has a significant effect on the chemical properties
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Homework
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