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A Flexible Supercapacitor with High True Performance
Zhonghua Ren, Yuanji Li, Jie Yu iScience Volume 9, Pages (November 2018) DOI: /j.isci Copyright © 2018 The Author(s) Terms and Conditions
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iScience 2018 9, 138-148DOI: (10.1016/j.isci.2018.10.016)
Copyright © 2018 The Author(s) Terms and Conditions
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Figure 1 A Schematic Illustrating Fabrication of TPNF
(A) Drilling through pores on a stainless steel sheet. (B) Sticking a tape on one side of the porous stainless steel sheet and pouring epoxy resin on the other side. (C) Standing for a while to make the pores fully filled with epoxy resin. (D) Peeling off the tape. (E) Obtained template. (F) Ni electrodeposition on template. (G) Ni stripping. See also Transparent Methods. iScience 2018 9, DOI: ( /j.isci ) Copyright © 2018 The Author(s) Terms and Conditions
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Figure 2 Characterization of Template and TPNF
(A and B) Low- (A) and high- (B) magnification scanning electron micrographs of porous stainless steel sheet. Scale bars: 500 μm in (A) and 200 μm in (B). (C) Scanning electron micrograph of template showing a pore filled with epoxy resin. Scale bar, 10 μm. (D and E) Scanning electron micrographs of front (D) and back (E) sides of TPNF. Scale bars, 200 μm. Insets: high-magnification scanning electron micrographs. Scale bars in insets, 20 μm. (F) Cross-sectional scanning electron micrograph of the TPNF deposited for 2 hr at 1 mA cm−2. Scale bar, 5 μm. (G) Optical image of a large-area TPNF (8 × 10 cm2) showing the translucency. Scale bar, 2 cm. (H) Optical image of the TPNF floating on water, indicating the lightness. Scale bar, 5 cm. (I and J) Optical images of the TPNF wrapped on a thin glass rod (I) and unfolded (J), showing the flexibility. Scale bars, 2 cm. See also Figure S1. iScience 2018 9, DOI: ( /j.isci ) Copyright © 2018 The Author(s) Terms and Conditions
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Figure 3 Materials Characterization of MnO2 Deposited on TPNFs
(A–D) Optical images of the electrodes deposited for 10 min (A), 20 min (B), 40 min (C), and 60 min (D). Scale bars, 1 cm. (E) Scanning electron micrograph of the electrode deposited for 60 min. Scale bar, 200 μm. Inset: higher magnification scanning electron micrograph. Scale bar in inset, 20 μm. (F and G) Scanning electron micrographs of MnO2 nanosheets deposited for 60 min at the rib (F) and pore (G) regions. Scale bars, 500 nm. (H) Scanning electron micrograph of the electrode deposited for 60 min taken by tilting the sample. Scale bar, 10 μm. (I and J) EDX mapping images of Mn (I) and O (J) elements taken from (G). Scale bars, 500 nm. (K) Composition distribution along a line shown in (G). (L) Optical image of the electrode deposited for 60 min under ultrasonic vibration. Scale bar, 1 cm. See also Figures S2–S8. iScience 2018 9, DOI: ( /j.isci ) Copyright © 2018 The Author(s) Terms and Conditions
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Figure 4 Electrochemical Characterization of MnO2 Electrodes
(A) CV curves of MnO2 nanosheets on TPNFs with different mass loadings at 100 mV s−1. (B) CV curves of MnO2 nanosheets on different current collectors with 8.2 mg cm−2 mass loading at 100 mV s−1. (C) GCD curves of MnO2 nanosheets on different current collectors with 8.2 mg cm−2 mass loading at 7 mA cm−2. (D) CV curves of MnO2 nanosheets on TPNF with 8.2 mg cm−2 mass loading at different scan rates. (E) Specific capacitances of MnO2 nanosheets on different current collectors with 8.2 mg cm−2 mass loading at different current densities. (F) Specific capacitances of MnO2 nanosheets on different current collectors with different mass loadings at 3.5 mA cm−2. (G) Cycling stability of the electrodes using different current collectors with 8.2 mg cm−2 mass loading tested at 17.5 mA cm−2. (H) Nyquist plots of the MnO2/TPNF electrodes with different mass loadings. Inset: equivalent fitting circuit and magnified Nyquist plots. (I) Nyquist plots of the electrodes using different current collectors with 8.2 mg cm−2 mass loading. Inset: magnified Nyquist plots. See also Figure S9. iScience 2018 9, DOI: ( /j.isci ) Copyright © 2018 The Author(s) Terms and Conditions
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Figure 5 Characterization of the Packaged Flexible Solid-State Supercapacitor (A) Diagram of a packaged full cell. (B) Cross-sectional scanning electron micrograph of the cell. Scale bar, 50 μm. (C) Matching of MnO2 and MoO3−x electrodes at 20 mV s−1. (D) CV curves of the cell at different scan rates. (E) GCD curves of the cell at different current densities. (F and G) Ragone plots of the cell based on the packaged cell weight (F) and volume (G). (H) Optical images of a light-emitting diode powered by two tandem cells with areas of 2 × 8 cm2 in different bending states. Scale bar, 2 cm. See also Figures S10–S22. iScience 2018 9, DOI: ( /j.isci ) Copyright © 2018 The Author(s) Terms and Conditions
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