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Erwin Schrodinger (1887 – 1961) H Y = E Y Wave Equation
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Wave Equation Solution for E
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Wave Equation Solution for Y
Ground State (n = 1)
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Wave Equation Solution for Y
First Excited States (n = 2)
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Wave Equation Solution for Y
d orbitals (n > 2)
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Wave Equation Solution for Y
f orbitals (n > 3)
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Splitting of Energy Levels
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Many Electron Energy Diagram
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Electron Configurations
H = 1s1 He = 1s2 Li = 1s2 2s1 Be = 1s2 2s2 B = 1s2 2s2 2p1 C = 1s2 2s2 2p2 N = 1s2 2s2 2p3 O = 1s2 2s2 2p4 F = 1s2 2s2 2p5 Ne = 1s2 2s2 2p6 Na = 1s2 2s2 2p6 3s1 Mg = 1s2 2s2 2p6 3s2 Al = 1s2 2s2 2p6 3s2 3p1 Si = 1s2 2s2 2p6 3s2 3p2 P = 1s2 2s2 2p6 3s2 3p3 S = 1s2 2s2 2p6 3s2 3p4 Cl = 1s2 2s2 2p6 3s2 3p5 Ar = 1s2 2s2 2p6 3s2 3p6 K = 1s2 2s2 2p6 3s2 3p6 4s1 Ca = 1s2 2s2 2p6 3s2 3p6 4s2 Sc = 1s2 2s2 2p6 3s2 3p6 4s2 3d1 etc.
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The Modern Periodic Table of the Elements
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Periodic Table of the Elements
Dimitri Mendeleev ( )
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Alkali Metals Element At. Weight mp (oC) D (g/mL) Oxide Chloride
Lithium 7 180 0.534 Li2O LiCl Sodium 23 98 0.968 Na2O NaCl Potassium 40 63 0.89 K2O RbCl Rubidium 86 39 1.53 Rb2O Cesium 133 28 1.93 Cs2O CsCl
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Alkaline Earth Metals Element At. Weight mp (oC) D (g/mL) Oxide
Chloride Beryllium 9 1287 1.85 BeO BeCl2 Magnesium 24 650 1.738 MgO MgCl2 Calcium 40 842 1.55 CaO CaCl2 Barium 137 727 3.51 BaO BaCl2 Radium (226) 700 5.5 RaO RaCl2
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Mendeleev’s Periodic Table
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Mendeleev’s Periodic Table
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Mendeleev’s Periodic Table of 1872
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Property Ekaaluminum Gallium atomic mass 68 69.72 density (g/cm³) 6.0 5.904 melting point (°C) Low 29.78 oxide's formula Ea2O3 (density g cm-3) (soluble in both alkalis and acids) Ga2O3 (density g cm-3) (soluble in both alkalis and acids) chloride's formula Ea2Cl6 (volatile) Ga2Cl6 (volatile)
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Diagonal Relationships
Lithium & Magnesium Carbonate are Sparingly Soluble in Water (Sodium, Potassium, Rubidium & Cesium Carbonates Very Soluble in Water) Lithium & Magnesium form Oxides when Exposed to Air (Sodium, Potassium, Rubidium & Cesium form Peroxides or Superoxides) Lithium & Magnesium for Stable Nitrides (Sodium, Potassium, Rubidium & Cesium do not) Lithium & Magnesium Chloride Precipitate from an Aqueous Solution as Hydrates (Sodium, Potassium, Rubidium & Cesium Chlorides do not)
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