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Ch 5 The Periodic Law 5.1 History of the Periodic Table
Mendeleev Proposed/arranged elements into rows based on increasing mass (like periods) and into columns due to similar properties (like groups) Prediction, not all elements discovered yet Left spaces for new elements!
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Mosley Working with Ernest Rutherford and spectra of metals Saw arranged by increasing nuclear charge, p+ Led to atomic number (not atomic mass) to organize periodic table Periodic Law: elements arranged in order of increasing atomic number, there is a periodic repetition of physical/chemical properties
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Noble Gases (18 or 8A, full p)
Added to periodic table, missed because unreactive Lanthanides (4f) 14 elements atomic # 58-71 Added in 1900s Actinides (5f) 14 elements atomic # Belong in pd 6-7 and groups 3-4, but placed below periodic table Periodicity Arrangement of e- around nucleus
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5.2 E- Configuration and the Periodic Table
Recall e- configurations/shapes See pattern of e- configuration in periodic table!
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s- orbital Alkali: Group 1 or 1A Alkaline earth metals: Group 2 or 2A
From Arabic al aquali= the ashes Metals with 1e- Highly reactive metals Alkaline earth metals: Group 2 or 2A Harder/denser with 2e- Still reactive H and He: s-block but gases/ do not share properties
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d- block elements Transition metals: Group 3-12 (B group elements)
Metals 80% periodic table Properties: good conductors heat/electricity, reflect light with luster/sheen, ductile, malleable
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p-block: Group 13-17 or 3A-7A Main- group elements
Non metals or metalloids Halogens: Group 7A or 17 are the most reactive non-metals Noble gas: Group 18 or 8A are the most stable elements
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f-block Inner transition metals Below main body of periodic table 14e-
Previously called rare-earth metals (misleading bc more abundant than other elements) Lanthanides Actinides
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5.3 E- Configuration and Periodic Properties
Atomic Radii: ½ distance between nuclei of identical bonded atoms Period: decreases as move from left to right in period Group: increases as move down group Same for atomic size!!!
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Ionization: Energy to remove e-
Period: increases from left to right in period Group: decrease from top to bottom in group
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Electron affinity: E added when an e- is added to neural atom; energy given off is neg #
Period: most periods except halogens gain e-; decreases left to right Group: added with greater difficulty down a group usually, increases down group
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Ionic radii: cations are smaller, anion are larger
Period: cations/anions decrease in size from left to right in period Group: increase in ionic radii from top to bottom in group
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Electronegativity: how easy to attract e-
Period: increases from left to right in a period Group: decrease from top to bottom in a group
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