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How does the probability density

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Presentation on theme: "How does the probability density"— Presentation transcript:

1 How does the probability density
look like at the nucleus? (A) There is a maximum at the nucleus for s-electrons, but it is zero for ℓ > 0 electrons with ℓ > 0 (p,d,f, etc.) (B) There is a maximum at the nucleus for all orbitals (C) The probability density is zero at the nucleus.

2 How does the probability density
look like at the nucleus? (A) There is a maximum at the nucleus for s-electrons, but it is zero for ℓ > 0 electrons with ℓ > 0 (p,d,f, etc.) (B) There is a maximum at the nucleus for all orbitals (C) The probability density is zero at the nucleus. ... because of the factor r2 in the above expression (r = 0 at the nucleus). This makes sense, because the Coulomb interaction energy of the electron and the nucleus would be infinitely large, which would be unphysical.

3 Consider the orbitals and radial functions shown below. From the
shape of the orbitals and the radial functions, try to develop an educated guess about the number of nodes in a H wave function. 2s 2pz n-1 radial, ℓ-1 angular (B) n-ℓ radial, ℓ angular (C) n-ℓ-1 radial, ℓ angular (D) n-1 radial, ℓ angular

4 Consider the orbitals and radial functions shown below. From the
shape of the orbitals and the radial functions, try to develop an educated guess about the number of nodes in a H wave function. 2s 2pz n-1 radial, ℓ-1 angular (B) n-ℓ radial, ℓ angular (C) n-ℓ-1 radial, ℓ angular (D) n-1 radial, ℓ angular


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