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Dodecahedrane Paquette, L. A. Chem. Rev. 1989, 89, 1051–1065.

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Presentation on theme: "Dodecahedrane Paquette, L. A. Chem. Rev. 1989, 89, 1051–1065."— Presentation transcript:

1 Dodecahedrane Paquette, L. A. Chem. Rev. 1989, 89, 1051–1065.

2 Dodecahedrane: Retrosyntheses

3 Dodecahedrane: Dimerization Schemes

4 Dodecahedrane: Dimerization Schemes

5 Dodecahedrane: Capping Schemes

6 Dodecahedrane: Retrosyntheses

7 Dodecahedrane: Retrosyntheses

8 Dodecahedrane: Retrosyntheses

9 Dodecahedrane: The Assembly of 20 Carbons

10 Dodecahedrane: Two Bonds Removed

11 Dodecahedrane: Two Bonds Removed

12 Dodecahedrane 4 Ternansky, R. J.; Balogh, D. W.; Paquette, L. A. J. Am. Chem. Soc. 1982, 104, 4503–4504. Paquette, L. A.; Balogh, D. W.; Usha, R.; Kountz, D.; Christopher, G. Science 1981, 211, 275.

13 Dodecahedrane: Isomerization Approaches
Fessner, W.-D.; Murty, B. A. R. C.; Worth, J.; Hunkler, D.; Fritz, H.; Prinzbach, H.; Roth, W. D.; Schleyer, P. von R.; McEwen, A. B.; Maier, W. F. Angew. Chem. Int. Ed. Engl. 1987, 26, 452.

14 Dodecahedrane: Isomerization Approaches


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