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Table 15-1, p. 612
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Common Names of Carboxylic Acids
Table 15.1
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Common Names of Dicarboxylic Acids
Table 15.1
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p. 614
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Table 15-2, p. 615
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p. 615
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Figure 15.1 An alkoxide ion has its charge localized on one oxygen atom and is less stable, while a carboxylate ion has the charge spread equally over both oxygens and is therefore more stable. Fig. 15-1, p. 616
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p. 616
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p. 618
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p. 618
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Figure 9.16 Classification of substituent effects in electrophilic aromatic substitution. All activating groups are ortho- and para-directing, and all deactivating groups other than halogen are meta-directing. The halogens are unique in being deactivating but ortho- and para-directing.
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Electrophilic Aromatic Substitution
Figure 9.16 Classification of substituent effects in electrophilic aromatic substitution. All activating groups are ortho- and para-directing, and all deactivating groups other than halogen are meta-directing. The halogens are unique in being deactivating but ortho- and para-directing. Fig. 9-16, p. 338
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pKa’s of Substituted Benzoic Acids
Lower pKa Higher pKa Figure 9.16 Classification of substituent effects in electrophilic aromatic substitution. All activating groups are ortho- and para-directing, and all deactivating groups other than halogen are meta-directing. The halogens are unique in being deactivating but ortho- and para-directing. Fig. 9-16, p. 338
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Preparation of Carboxylic Acids : Review
Oxidation of 1 alcohols: a. CrO3, H3O+ b. K2Cr2O7, H2SO4 Oxidation of 1 alcohols: p. 620
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Preparation of Carboxylic Acids : Review
2. Oxidation of aldehydes: a. KMnO4 b. CrO3, H3O+ c. K2Cr2O7, H2SO4 (Jones) Oxidation of 1 alcohols: p. 620
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Preparation of Carboxylic Acids : Review
3. Oxidative cleavage (of double bonds): a. KMnO4 b. O3, H2O2 Oxidation of 1 alcohols: p. 620
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Preparation of Carboxylic Acids : Review
3. Oxidative cleavage a- to arene: a. KMnO4 b. CrO3, H3O+ Oxidation of 1 alcohols: Methyl, 1° , 2°
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Figure 15.4 IR spectrum of butanoic acid, CH3CH2CH2CO2H. Fig. 15-4, p. 627
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p. 628
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Figure 15.5 Proton NMR spectrum of phenylacetic acid, C6H5CH2CO2H. Fig. 15-5, p. 628
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