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Table 15-1, p. 612.

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Presentation on theme: "Table 15-1, p. 612."— Presentation transcript:

1 Table 15-1, p. 612

2 Common Names of Carboxylic Acids
Table 15.1

3 Common Names of Dicarboxylic Acids
Table 15.1

4 p. 614

5 Table 15-2, p. 615

6 p. 615

7 Figure 15.1 An alkoxide ion has its charge localized on one oxygen atom and is less stable, while a carboxylate ion has the charge spread equally over both oxygens and is therefore more stable. Fig. 15-1, p. 616

8 p. 616

9 p. 618

10 p. 618

11 Figure 9.16 Classification of substituent effects in electrophilic aromatic substitution. All activating groups are ortho- and para-directing, and all deactivating groups other than halogen are meta-directing. The halogens are unique in being deactivating but ortho- and para-directing.

12 Electrophilic Aromatic Substitution
Figure 9.16 Classification of substituent effects in electrophilic aromatic substitution. All activating groups are ortho- and para-directing, and all deactivating groups other than halogen are meta-directing. The halogens are unique in being deactivating but ortho- and para-directing. Fig. 9-16, p. 338

13 pKa’s of Substituted Benzoic Acids
Lower pKa Higher pKa Figure 9.16 Classification of substituent effects in electrophilic aromatic substitution. All activating groups are ortho- and para-directing, and all deactivating groups other than halogen are meta-directing. The halogens are unique in being deactivating but ortho- and para-directing. Fig. 9-16, p. 338

14 Preparation of Carboxylic Acids : Review
Oxidation of 1 alcohols: a. CrO3, H3O+ b. K2Cr2O7, H2SO4 Oxidation of 1 alcohols: p. 620

15 Preparation of Carboxylic Acids : Review
2. Oxidation of aldehydes: a. KMnO4 b. CrO3, H3O+ c. K2Cr2O7, H2SO4 (Jones) Oxidation of 1 alcohols: p. 620

16 Preparation of Carboxylic Acids : Review
3. Oxidative cleavage (of double bonds): a. KMnO4 b. O3, H2O2 Oxidation of 1 alcohols: p. 620

17 Preparation of Carboxylic Acids : Review
3. Oxidative cleavage a- to arene: a. KMnO4 b. CrO3, H3O+ Oxidation of 1 alcohols: Methyl, 1° , 2°

18 Figure 15.4 IR spectrum of butanoic acid, CH3CH2CH2CO2H. Fig. 15-4, p. 627

19 p. 628

20 Figure 15.5 Proton NMR spectrum of phenylacetic acid, C6H5CH2CO2H. Fig. 15-5, p. 628


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