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5.1 – ELECTRONS IN ATOMS.

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1 5.1 – ELECTRONS IN ATOMS

2 5.1 WAVE NATURE OF LIGHT: Important in understanding electrons.
Electromagnetic radiation – Form of energy which includes visible light, microwaves, X-rays, radio waves, etc.

3 ELECTROMAGNETIC RADIATION TRAVELS IN WAVES
Wavelength () – distance between 2 waves Units: m, cm, nm (1nm = 1 x 10-9 m) Frequency () - # waves that pass a given point per second Units: waves/sec, hertz (1 wav/s = 1 hz) Amplitude - wave’s height from origin (middle) to crest.

4 VELOCITY: All electromagnetic radiation travels at the speed of light, “c”.
c = 3.00 x 108 m/s c =  Wavelength & frequency: inversely proportional If wavelength increases, frequency decreases.

5 c =  (solving for wavelength, , lambda)
PROBLEM: Find wavelength of a microwave having a frequency of 3.44 x 109 Hz? c =  (solving for wavelength, , lambda) c = 3.00 x 108 m/s (constant)  = 3.44 x 109 Hz (s-1or per second) Plug into equation: 3.00 x 108 m/s =  x x 109/s 3.00 x 108 m/s =  3.44 x 109/s  = 8.72 x 10-2 m

6 PROBLEM: Find the frequency of green light which has a wavelength of 4
PROBLEM: Find the frequency of green light which has a wavelength of 4.90 x 10-7 m. c =  (solving for frequency, , nu) c = 3.00 x 108 m/s (constant)  = 4.90 x 10-7 m Plug in: 3.00 x 108 m/s = 4.90 x 10-7 m x  3.00 x 108 m/s =  4.90 x 10-7 m  = 6.12 x 1014s-1 (or Hertz)

7 WHITE LIGHT: Prism separates into a continuous spectrum -- ROYGBIV
Red light – lower frequency (longer wavelength) than violet light.

8 QUIZ 1) Name 3 types electromagnetic radiation.
2) What is the velocity of all electromagnetic radiation? 3) The distance between waves is ____(). 4) The number waves per second is ___(). 5) The higher the frequency, the ___the wavelength. 6) A prism separates white light into the ___ spectrum.

9 ELECTROMAGNETIC RADIATION

10 Iron – dark gray at room temperature
PARTICLE NATURE OF LIGHT: Explains why heated objects emit specific frequencies of light. Iron – dark gray at room temperature red when hotter, bluish when v. hot. (Photon of light)

11 MAX PLANCK (1900) – Quantum concept of energy:
Matter gains or loses energy in small specific amounts called quanta. Quantum – minimum amount of energy that can be gained/lost by an atom. Equation: E = h Where: E = energy (joules) h = Planck’s constant 6.626 x js  = frequency

12 E = h Frequency & energy are directly proportional.
High frequency, high energy (small wavelength) Energy: In whole number multiples of h. If energy decreases, what happens to ? How is  related to energy?

13 PROBLEM: Find energy of photon of violet light having frequency of 7
PROBLEM: Find energy of photon of violet light having frequency of 7.23 x 1014/sec. E = h (E is unknown) h = Planck’s constant = x js Plug in: E = x js x 7.23 x 1014s-1 E = 4.79 x J (ans.) (joule)

14 Effect explained by Einstein (1905):
PHOTOELECTRIC EFFECT: Light shining on a metal’s surface results in emission of (photo) electrons. Ex. Solar calculator – converts light into electrical energy Effect explained by Einstein (1905): Light has particle & wave nature. Photons – stream of tiny particles of light. Bundles of energy. No mass. Ephoton = h (Planck)

15 ATOMIC EMISSION SPECTRA: Set of frequencies of electromagnetic waves emitted by atoms of an element.
Spectrum is unique for each element. Ex. Sr atoms – Emit a characteristic red color. Can use spectrum to identify an element. Atomic spectrum consists of several individual lines of color (Not continuous).

16 Elements emit a characteristic color.
When the element is heated, electron moves to higher energy level. (excited) When electron returns to the ground state, a photon of light is emitted corresponding to the difference in energy.

17

18 QUIZ 1) Light has a wave nature and a ___nature.
2) According to Planck’s equation, the higher the frequency, the ___ the energy. This is ___ proportional. 3) The set of frequencies emitted by atoms of an element is called the atomic ____ _____. 4) In the flame tests, what causes the characteristic color of the element?

19 THE END


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