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Published byIrwan Sutedja Modified over 5 years ago
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LAW OF HESS H.W. 10/10/07 C A B B C B A C A ∆H1= +30kJ ∆H2= +60kJ
5.60 C A B ∆H1= +30kJ ∆H2= +60kJ B C ∆H2= +60kJ B A C ∆Hreact= +90kJ ∆Hreact= +90kJ ∆H1= +30kJ B cross cancels across the arrow. To do so, the compound and phase must be the same. A
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MULTIPLY BY 3/2 TO CANCELL THE O2
5.62 2H2 O2(g) ∆H1= kJ + 2H2O ∆H2= kJ 3 O2 (g) 2O3 REVERSE THIS TO GET O3 AS A REACTANT, THEN MULTIPLY BY 1/2 TO CANCELL THE O2, RECIPROCATE SIGN OF ∆H WHEN YOU REVERSE A REACTION MULTIPLY BY 3/2 TO CANCELL THE O2 3H2 3/2 O2(g) + 3H2O ∆H1=3/2 ( kJ) O3 3/2 O2 (g) ∆H2=1/2 ( kJ) 3H2 O3 + 3H2O ∆H= ( kJ)
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MULTIPLY BY 3/2 TO CANCELL THE O2
5.62 2H2 O2(g) ∆H1= kJ + 2H2O ∆H2= kJ 3 O2 (g) 2O3 REVERSE THIS TO GET O3 AS A REACTANT, THEN MULTIPLY BY 1/2 TO CANCELL THE O2, RECIPROCATE SIGN OF ∆H WHEN YOU REVERSE A REACTION MULTIPLY BY 3/2 TO CANCELL THE O2 3H2 3/2 O2(g) + 3H2O ∆H1=3/2 ( kJ) O3 3/2 O2 (g) ∆H2=1/2 ( kJ) 3H2 O3 + 3H2O ∆H= ( kJ)
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