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Heat Calculations Q = mHv & Q = mHf
You will need a calculator and your shoulder partner
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Objective Students will calculate the amount of heat by using the formulas Q = mHf and Q = mHv and content language (heat, mass, heat of vaporization, heat of fusion (melting)) supports include class notes, calculator, background knowledge from math class and shoulder partners.
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Heating Curve/Phase Changes
Exothermic: Down the heating curve Losing Heat Energy CONDENSATION VAPORIZATION GAS LIQUID FREEZING MELTING Endothermic: Up the heating curve Gaining Heat Energy SOLID
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Endothermic Gaining Energy Going UP the heating curve
Reactants have LESS energy than products (pg. 538) POSITIVE Hf or Hv
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Exothermic Losing Energy Going DOWN the heating curve
Reactants have MORE energy than products NEGATIVE Hf or Hv
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Heating Curve Heat of Fusion Q = mHf Hf = 80 cal/g
Heat of Vaporization Q = mHv Hv = 540 cal/g
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Q = mHf Use if the question uses the word “freezes” or “melts” (1st straight line on heating curve) Q = Heat or Heat Energy Units: Joules or Calorie m = Mass Units : grams Hf = Heat of Fusion ALWAYS: 80 cal/g if “melting” - 80 cal/g if “freezing”
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I Do: Q = mHf Read the question:
How much energy is released when 20.0 g of water is frozen at 0oC? Find your Q, m, Hf from the question. Q = ? m = 20.0 g Hf = -80 cal/g Q = (20.0 g) (-80 cal/g) Q = cal
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We Do: Q = mHf Read the question:
How much energy is required to melt 25.9 g of ice at its melting point? Find your Q, m, Hf from the question. Q = ? m = Hf =
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Q = mHv Use if the question uses the word “vaporizes” OR “condenses” (2nd straight line of heating curve) Q = Heat or Heat Energy Units: Joules or Calorie m = Mass Units : grams Hv = Heat of Vaporization ALWAYS: 540 cal/g if “vaporizing” - 540 cal/g if “condensing”
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I Do: Q = mHv Read the question:
Determine the amount of heat (Q) needed to vaporize 300 g of water at 100oC. Find your Q, m, Hv from the question. Q = ? m = 300 g Hv = 540 cal/g Q = (300 g) (540 cal/g) Q = 162,000 cal or 162 Kcal
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We Do: Q = mHv Read the question:
How much energy is released when 23.5 g of steam is condensed at 100oC? Find your Q, m, Hv from the question. Q = ? m = Hv =
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Heating Curve Q = mHv Hv = 540 cal/g Q = mHf Q=mcΔT (cliquid =
Hf = 80 cal/g Q=mcΔT (cliquid = 1 cal/g oC) Q=mcΔT (cice = 0.5 cal/g oC)
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“I Do”… Calculate the TOTAL amount of heat required to completely convert 50 g of ice at -10 ºC to steam at 100 ºC. Step 1: Draw a heating curve… Q=mHv 100oC 100oC Q=mcΔT 0oC Q=mHf - 10oC Q=mcΔT
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This questions takes 4 steps… (4 lines on the heating curve)
Step 1: First Line: Heat taken up heating the ice from -10 ºC to the melting point, 0 ºC. Q=mcΔT: Q = (50g) x (0.5 cal/g oC) x(10 oC) = 250 cal Step 2: Second Line: Heat taken up for converting ice from 0 ºC to water at 0 ºC. Q=mHf: Q = (50g) x (80 cal/g) = 4,000 cal Step 3: Third Line: Heat taken up heating the water from 0 ºC to the boiling point, 100 ºC Q = mcΔT: Q = (50g) x (1 cal/g oC) x (100 oC) = 5,000 cal Step 4: Forth Line: Heat taken up vaporizing the water. Q = mHv: Q = (50g) x (540 cal/g) = 27,000 cal Step 5: Add ALL the HEAT: 250 cal + 4,000 cal + 5,000 cal + 27,000 cal = 36,250 cal
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“YOU DO….” Calculate the amount of heat required to completely convert 25 g of ice at -5 ºC to steam at 100 ºC. Step 1: Draw a heating curve… Step 2: Q = mcΔT Step 3: Q = mHf Step 4: Q = mcΔT Step 5: Q = mHv Step 6: Add all the Q’s up
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