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VI. Polarity
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A. Polarity The bonding pairs of electrons in covalent bonds are pulled by the nuclei
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A. Polarity Cont. Electronegativity values determine the charge distribution in a covalent bond electronegativity: a measure of an atom’s attraction for electrons
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B. Nonpolar Covalent Bond
Bond between two nonmetal atoms with the same (or extremely close) electronegativity. Bonded electrons are shared equally Ex: H2, O2, N2
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C. Polar Covalent Bond Bond between 2 nonmetal atoms with different electronegativity values. Bonded electrons are shared unequally. Atom with higher electronegativity pulls more strongly and has a partial negative charge Atom with lower electronegativity pulls less strongly and has a partial positive charge
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D. Polar Molecules In a polar molecule, one end of the molecule is slightly negative and the other end is slightly positive. A molecule that has two poles (opposite charges) is called a dipolar molecule, or dipole.
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E. Determining Polar/Nonpolar/Ionic
Use difference in electronegativity values to determine the type of bond. Difference Type of Bond 0.0 – 0.4 Nonpolar covalent 0.4 – 1.0 Moderately polar covalent 1.0 – 2.0 Very polar covalent ≥ 2.0 Ionic
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Example #1 Determine the type of bond between H and Cl.
H = 2.1 Cl = 3.0
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H and Br C and O Br and Br K and Cl P and F Example 2
H = 2.1 Br = 3.0 C = 2.5 O = 3.5 K = 0.8 Cl = 3.0 P = 2.1 F = 4.0 H and Br C and O Br and Br K and Cl P and F
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