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Published byWidyawati Sugiarto Modified over 5 years ago
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Colors and Spectroscopy of Transition Metal Complexes
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Spectrochemical Series:
Sigma Interaction Strength Spectrochemical Series: I- < Br - < Cl- , F- < OH- < OH2 < NH3 < en < CN- < CO
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Pi Donor Ligands: Mainly oxides and halides
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Mn2+(aq) MnO4 -
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Pi Acceptor Ligands: CO, CN-, pyridine
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Pi Acceptor Ligands and spectroscopy: CO, CN-, pyridine
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Reactivity of Transition Metal Complexes
Substitution Reactions Redox Reactions Photochemically-Induced Reactions
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Substitution Reactions: why would they occur?
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Catalysis Homogeneous vs. Heterogeneous
Transition metal complex catalysis
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