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Nomenclature Naming Compounds
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Binary Compounds
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Compounds with only two elements in any ratio
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KCl NO2 CaCl2 P2O5 Al2O3 H2S Na2O etc
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Binary compounds can be either ionic or covalent
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Naming Binary Compounds
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Naming Ionic Compounds
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Name positive element first with its normal name
Name negative element last & change its ending to -ide
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KCl CaCl2 Al2O3 Na2O
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Name Each: CaCl2 CaS K2O LiF
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Name Each: FeCl2 FeCl3
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If the Positive element is not from columns I or II
its ox # must be determined and written in roman numerals
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Determining the Charge
Add up the oxidation numbers of all the negative elements The positive portion must balance out the negative portion Divide the positive portion by the metal subscript
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Name Each: CuCl Fe2O3 MnO2 CrO3
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Molecule
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A covalent compound that can exist as a separate unit
Non-metals bond to form molecules
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Naming Molecules or Covalent Compounds
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Same rules as ionic compounds except:
use geometric prefixes to determine the # of each atom
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Geometric Prefixes 1-mono 5-penta 2-di 6-hexa 3-tri 7-hepta
4-tetra etc
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Name Each: CO S2O3 N2H4 SO3
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Nomenclature HW Work problems: on page 51
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Drill: Name Each: CaO P2O5 Al2S3 SO2
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Deriving Formulas Write the symbol for each element
Determine ox #s for each Determine lowest common multiple to balance the charge Apply subscripts
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Write formulas for: Sodium sulfide Lead (II) iodide Diphosphorus
pentoxide
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Write formulas for: Chromium(III) oxide Aluminum carbide
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Polyatomic Ion
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A group of atoms chemically combined that together have a charge
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Most are oxoanions PO4-3 SO4-2 A root element bound to oxygen
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Drill: Name each CuCl2 KBr PCl5 MgO Mn2O7 S2O3
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Naming Polyatomic Ions
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Learn the polyatomic table on page 42 & 43
Learn how to use the periodic table to determine polyatomic ions
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Name the root element Change the ending to -ate PO4-3 = phosphate Some are unusual
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CN-1 OH-1 C2H3O2-1 C2O4-2
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H2O H3O+1 NH3 NH4+1
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Polyatomic Ion Endings
Maximum O = -ate 1 less than max O = -ite SO4-2 = sulfate SO3-2 = sulfite
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Naming Ternary Compounds
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Ternary Compounds Compounds containing more than two different elements Most contain polyatomic ions
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Follow ionic rules for naming the compound
Name the polyatomic ion as the positive or negative portion
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Name Each: CaCO3 K2SO4
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Drill: Name: Pb(NO3)2 MgSO3
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Write Formulas For: Lead (II) nitrate Aluminum sulfate
Potassium chlorate Ammonium phosphite
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Name the Following: BaSO4 CuNO3 SO (NH4)3PO4
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Naming Acids
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Binary acids become: Hydro _____ ic acids HCl - Hydrochloric acid
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Ternary acids become: _____ ic acids or _____ ous acids H2SO4 - Sulfuric acid H2SO3 - Sulfurous acid
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____ ic acids form from polyatomic ions ending with ___ ate
____ ous acids form from polyatomic ions ending with ___ ite
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___ ide ions become: hydro ___ ic acids ___ ate ions become: ___ ic acids ___ ite ions become: ___ ous acids
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Name or Give Formulas For:
HBr(aq) H2SO4(aq) NaVO3 (NH4)3PO3 Phosphoric acid Nitric acid Chloric acid
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Drill: Name each: KBr MgS BaF2 K3P K2O LiH Al2O3 H2S
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Derive formulas for each:
Cesium oxide Barium chloride Calcium phosphide Aluminum sulfide
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Name each of the following:
SeO CS2 NO2 Cl2O N2O4 PCl3
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Derive formulas for each:
Silicon dioxide phosphorus trichloride Sulfur hexafluoride Iodine trifluoride
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Name each of the following:
SO SO3-2 PO NO3-1 ClO ClO3-1 ClO ClO-1
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Derive formulas for each:
Chromate Sulfate Arsenate Nitrate Arsenite Cyanide Bromite Acetate
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Name each of the following:
HCl H2SO4 H2S H3PO3 HNO3 HBrO H2CO3 HBrO4
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Derive formulas for each:
Chromic acid Hydroiodic acid Sulfurous acid Bromic acid
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Name each of the following:
CuO MnS PbO2 Cu2O CrCl2 MnF2 CrCl3 SnCl4
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Percent Composition by Mass
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Determine the atomic mass of each element in the compound
Determine the molecular mass of the compound by adding Divide each elemental mass by molecular mass Multiply by 100 %
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MgCl2 Mg = 24.3 g/mole 2 Cl = 2 x 35.5 = 71.0 g/mole MgCl2 = total = 95.3 g/mole % Mg =24.3/95.3 x 100% % Cl = 71.0/95.3 x 100 %
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Determine % Comp for Each:
Fe2O3 C3H6O3 CuSO4*5H2O
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Drill: Determine % Comp for Each:
C3H6O3 CuSO4*5H2O
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Name each of the following:
FeO Fe2O3
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Derive formulas for each:
Lead(IV)oxide Copper(II)sulfide Manganese(VII)oxide Nickel(II)fluoride
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Name each of the following:
BaCO3 KNO2 CuClO3 Al2(SO4)3
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Derive formulas for each:
Potassium sulfate Lead(II)chromate Aluminum hydroxide Ammonium cyanide
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Name each of the following:
Cl2O SO2 N2O3 P2O5 CO2 CO SO3 N2H4
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Name each of the following:
NH4Cl BaSO4 KC2H3O2 K2HPO3 KNO3 CuBrO Li2CO3 MgC2O4
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Name each of the following:
KCl MnSO4 SO2 HI(aq) NaNO3 HClO H2CO3(aq) NH4BrO4
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Name each of the following:
NaCl MnSO4 S2O HBr(aq) Na2CO3 HClO HNO3(aq) NH4IO4
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Chapter 3 General Define all the Key Terms on page 74
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Nomenclature Work problems 43 – 56 On Pages 51 & 52
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