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Ideal gas: Statistical mechanics
Temperature is related to averaged kinetic energy For each of projections (degrees of freedom):
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Theorem of Equipartition of Energy:
Statistical mechanics Theorem of Equipartition of Energy: Each degree of freedom contributes ½kT to the energy of a system, where possible degrees of freedom are those associated with translation, rotation and vibration of molecules
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Boltzmann Distribution:
Statistical mechanics Boltzmann Distribution: Distribution function (number density) nV(E): It is defined so that nV(E) dE is the number of molecules per unit volume with energy between E and E + dE Probability P(E): It is defined so that P(E) dE is the probability to find a particular molecule between E and E + dE
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Statistical mechanics
Free particle: Harmonic oscillator:
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Averaged values: Averaged energy: Averaged velocity: Usually:
Statistical mechanics Averaged values: Averaged energy: Averaged velocity: Usually:
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