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Challenges for the Solar Manufacturing in India
Dr. Debajyoti Sarangi PI Photovoltaic-Institute (Suzhou) Co., Ltd. Building A, 2 Kezhi Road, Suzhou Industrial Park Suzhou, Jiangsu Province, China Borealis Polyolefine GmbH | St.-Peterstraße 25 | A-4021 Linz | Austria
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How much Solar Energy? About half the incoming solar energy reaches the Earth's surface. The earth receives more energy from the sun in just one hour than the world uses in a whole year
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What is Solar Cell? Mono c-Si Wafer Solar cell (>20%) Multi c-Si Wafer Solar cell (>18%)(~19%) A solar cell is an electronic device which directly converts sunlight into electricity. Also known as Photovoltaic (PV) Cell. Efficiency: Out put power / Incident Solar Energy
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Solar Manufacturing Sections
Polysilicon Sand Polysilicon / pure silicon Crystal Growth Multi Mono Wafering Multi Mono Solar Cell Solar Module
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Gaps in Solar Manufacturing
Polysilicon Requirement: 18 – TPA Planned: 1250 TPA Main challenge: High Capex, Cost of Power, Long gestation period Wafer 2.5 Bn/yr 600 Mn/yr Main challenge: High Capex, Power Cost, Technology choice Cell 6000 MW/yr Existing: 1200 MW/yr 2000 MW/yr Main challenge: Cost competitivenes, Quality. Module 5600 MW/yr Main challenge: Supply chain of components, cost competitiveness Inverter 6000 MW/yr to MW/yr 3500 MW/yr Main challenge: Supply chain for components Polysilicon production is an energy-consuming process ( kWh/kg) and needs reliable power sources for continuous operations
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Components of Solar Module
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Warranty
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Failure Scenarios of PV Module
Typical failure scenarios for crystalline silicon wafers based PV modules (Source: IEA-PVPS T13-01:2014)
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Light Induced Degradation (LID)
p-type wafer n+ emitter Al-BSF Mono Al BSF PERC Poly or multi p-type wafer n+ emitter Cause? Mono: B-O defects Poly PERC: ??? LeTID (light-and-elevated- temperature-induced degradation) Prevention : Hydrogen passivation treatment Include LID loss and do the calculations PERC (Passivated Emitter Rear Contact)
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Encapsulant : Ethylene Vinyl Acetate - EVA
Deacetylation and hydrolysis of vinyl-acetate monomers in EVA resulted in generating acetic acid, resulting: accelerate the corrosion of electrical interconnects deteriorate the transparency coating of the cells result in the eventual reduction in module performance Ethylene (vinyl acetate), EVA, is a copolymer that can be hydrolyzed under the presence of high temperatures, UV and moisture
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Exposed to 125°C for 14 days in air circulation oven
Avoid Yellowing of EVA Borealis encap EVA Ref 1 Ref 2 Exposed to 125°C for 14 days in air circulation oven Glass/Encapsulant/Glass Two industry reference EVA’s have been tested & show both degradation after 14 days of exposure to 125°C
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Eliminate corrosions: Avoid EVA
Test conditions: 70°C, 65% RH, 150 W/m2 UV dose. (actual module temperature ~85°C due to illumination). BPO EVA UV-absorber 0 h 2000 h
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Potential Induced Degradation (PID)
For the PID effect, charges moving from the glass plate through the EVA encapsulation and the ARC (Anti-Reflective Coating) to the cell Left Image: EL images of the PV modules before and PID test. Test Criteria: PV module subject to ±1000 V (DC) inside a climate chamber at 85% rH and 85ºC, for 96h. Power degradation <5% Encapsulant: replace EVA with POE like Borealis Quentys
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Snail Trails Cause? Ag nanoparticles agglomerations Source:
Front contacts: Grid lines EVA (Ethylene vinyl acetate) Preventation: Use of acetate free encapsulant like POE based Borealis Quentys BPO
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Sequential testing: Degradation of module
Modules are exposed to humidity, temperature variations & UV radiation Encapsulant type Initial power output Output after 4th cycle Degradation (%) BPO 253,4W 239,6W 5,4% EVA 252,6W 168,3W 33,4%
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Thank you for your attention!
More information Ph:
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The future with PV…
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