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Published byΣαμουήλ Γκόφας Modified over 5 years ago
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Eigenvalues and eigenvectors of a hydrogen atom
PHY 741 Quantum Mechanics 12-12:50 PM MWF Olin 103 Plan for Lecture 17: Chapters 13 Eigenvalues and eigenvectors of a hydrogen atom Quantum mechanics of atoms more generally 10/09/2017 PHY 741 Fall Lecture 17
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Quantum mechanics of the hydrogen atom z
re RN y x 10/09/2017 PHY 741 Fall Lecture 17
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Quantum mechanics of the hydrogen atom
z In center of mass coordinates r y x 10/09/2017 PHY 741 Fall Lecture 17
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Example of normalized radial functions Rnl(r):
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Hydrogen radial wavefunctions
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What about multi-electron atoms?
Digression – approximate analysis using variational methods A very powerful tool for estimating eigenvalues and eigenvectors is based on transforming the problem into a variational form 10/09/2017 PHY 741 Fall Lecture 17
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Back to estimate of wavefunction for He atom
Trial function for this case: 10/09/2017 PHY 741 Fall Lecture 17
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