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Chapter 4 Adel M. Awadallah Islamic University of Gaza
Organic chemistry for medicine and biology students Chem 2311 Chapter 4 Aromatic Compounds By Prof. Dr. Adel M. Awadallah Islamic University of Gaza
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Hydrocarbons (contain only carbon and hydrogen)
Aromatic Compounds Hydrocarbons (contain only carbon and hydrogen) Saturated: (Contain only single bonds) Alkanes (CnH2N + 2 ) Cycloalkanes (CnH2N ) b) Unsaturated: contain Alkenes: double bonds (,,,CnH2N) Alkynes: triple bonds ((CnH2N - 2) Aromatic: benzene like compounds
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Facts about double and triple bonds
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Structure of Benzene Benzene is the parent of a class of especially stable compounds called aromatic compounds. It was first isolated by Faraday in 1825 from compressed illuminating gas Different structures were suggested for benzene (C6H6). The regular conjugated hexagon structure was suggested by Kekuli` in 1865
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Orbital Model for Benzene
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Nomenclature of Aromatic Compounds
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Disubstituted Benzene
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Assigning Priority Halogens < alkanes < alkenes < amines < OH < ketone < aldehyde < acid < ester Examples
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Aromatic Compounds in Nature and Health
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Reaction of benzene with n-propyl chloride produces isopropyl benzene because of rearrangement
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How can you prepare the following compound? Starting from benzene
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Polycyclic aromatic compounds cigarettes
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C60, An aromatic sphere The Fullerenes
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