1. Chapter 23 Substitution Reactions of Carbonyl Compounds
at the  Carbon

2. 1. Introduction

3. 2. Enols

5. Tautomerization is catalyzed by both acid and base.

7. 3. Enolates

13. 4. Enolates of Unsymmetrical Carbonyl Compounds

14. 5. Racemization at the  Carbon
p. 894
p. 894

15. 6. Reactions of Enolates—Halogenation at the  Carbon

18. 7. Reactions of Enolates—Direct Enolate Alkylation

19. The stereochemistry of enolate alkylation

20. less substituted kinetic enolate, which then reacts with CH3I to form A.

21. the more substituted thermodynamic enolate, which then reacts with CH3I to form B.

22. 9. Reactions of Enolates—Malonic Ester Synthesis

28. 10. Reactions of Enolates—Acetoacetic Ester Synthesis