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Types of Chemical Reactions
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E.Q.: What are the different types of chemical reactions and how can I predict the products?
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Got that? SINGLE PRODUCT
A. Synthesis Two or more substances react to produce a single product. Got that? SINGLE PRODUCT A + B AB +
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A. Synthesis H2(g) + Cl2(g) 2 HCl(g)
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2 Fe(s) + Cl2(g) → FeCl3(s) 3 2 A. Synthesis
Iron and chlorine gas react to form iron(III) chloride. 2 Fe(s) + Cl2(g) → FeCl3(s) 3 2
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Al(s)+ Cl2(g) 2 3 2 AlCl3(s) A. Synthesis Products:
ionic – remember to cancel charges covalent - hard to tell if names are not provided Al(s)+ Cl2(g) AlCl3(s)
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CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
B. Combustion Oxygen reacts with a substance and releases energy in the form of heat and light. O2 is always a reactant A + O2 B CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
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B. Combustion 4 2 Na2O(s) Na(s)+ O2(g) C3H8(g)+ O2(g) 5 3 4
Products: contain oxygen hydrocarbons produce CO2 + H2O Na(s)+ O2(g) Na2O(s) Note: this reaction is also a synthesis reaction! C3H8(g)+ O2(g) CO2(g)+ H2O(g)
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Carbon is burned in oxygen to form carbon dioxide gas.
B. Combustion Remember: oxygen is always a reactant, and product(s) will always contain oxide. Carbon is burned in oxygen to form carbon dioxide gas. C(s) + O2(g) → CO2(g)
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B. Combustion of Hydrocarbon
All hydrocarbons contain carbon and hydrogen and burn in oxygen to yield the same products – carbon dioxide and water. CH4(g) + O2(g) → CO2(g) + H2O (g) 2 2
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AB A + B + C. Decomposition Only one reactant
A single compound breaks down into 2 or more simpler substances Only one reactant AB A + B +
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C. Decomposition 2 H2O(l) 2 H2(g) + O2(g)
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C. Decomposition KBr(l) 2 2 K(s) + Br2(l) Products:
binary - break into elements others - hard to tell KBr(l) K(s) + Br2(l)
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C. Decomposition Decomposition often requires an energy source, such as heat, light, or electricity, to occur. For example, ammonium nitrate breaks down into dinitrogen monoxide and water when heated to a high temperature. NH4+ NO3- → N2 O + H2O NH4NO3(s) → N2O(g) + 2H2O(g)
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A + BC AC + B + + D. Single Replacement
Atoms of one element replace the atoms of another element in a compound. metal replaces metal (+) nonmetal replaces nonmetal (-) A + BC AC + B + +
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Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s)
D. Single Replacement Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Copper replaces silver
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D. Single Replacement Balance this equation:
Potassium replaces hydrogen; therefore, potassium must be higher (more reactive) on the activity series list than hydrogen. Balance this equation: K(s) + H2O(l) → KOH(aq) + H2(g)
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D. Single Replacement Fe(s)+ CuSO4(aq) Cu(s)+ FeSO4(aq)
Products: metal metal (+) nonmetal nonmetal (-) free element must be more active (check activity series) Fe(s)+ CuSO4(aq) Cu(s)+ FeSO4(aq) Br2(l)+ NaCl(aq) N.R.
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Activity Series - A metal will not always replace another metal in a replacement reaction - Different metals have different reactivities, which is the ability of a metal to react with another substance - Metals are arranged by their reactivities in an activity series - This tool helps determine if a chemical reaction will take place and determining the result of a replacement reaction
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Activity Series
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Activity Series: How to read it?
- A specific metal can replace any metal listed below it that is in a compound - It cannot replace another listed above it The letters NR (no reaction) are usually used to show that a reaction cannot take place Ag (s) Cu(NO3)2 (aq) NR
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Activity Series Cu (s) AgNO3 (aq) Ag(s) + Cu(NO3)2 (aq) Copper is above silver in the series, meaning it can replace silver in a replacement reaction
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Activity Series Ag (s) + Cu(NO3)2 (aq) NR
Silver is below copper in the series, meaning it cannot replace copper in a replacement reaction
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AB + CD AD + CB + + E. Double Replacement
ions in two compounds “change partners” cation of one compound combines with anion of the other Reactions take place in aqueous solutions AB + CD AD + CB + +
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Pb(NO3)2(aq) + K2CrO4(aq) PbCrO4(s) + 2KNO3(aq)
E. Double Replacement Pb(NO3)2(aq) + K2CrO4(aq) PbCrO4(s) + 2KNO3(aq)
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E. Double Replacement 2 2 Pb(NO3)2(aq)+ KI(aq) PbI2(s)+ KNO3(aq)
Products: switch negative ions one product must be insoluble (check solubility table) Pb(NO3)2(aq)+ KI(aq) PbI2(s)+ KNO3(aq) NaNO3(aq)+ KI(aq) N.R.
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Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s)
What Type of Reactions? Pb(NO3)2(aq) + K2CrO4(aq) PbCrO4(s) + 2KNO3(aq) C(s) + O2(g) → CO2(g) Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s)
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H2(g) + Cl2(g) 2 HCl(g) 2 H2O(l) 2 H2(g) + O2(g)
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Try these……. ____ NaBr + ____ Ca(OH)2 ___ CaBr2 + ____ NaOH
Reaction Type : ______________________________ ____P4 + ____O2 _____P2O3 Reaction Type : _____________________ ____CaCO3 ____CaO + ____CO2 Reaction Type : _____________________
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Try these……. ____ Pb + ____ H3PO4 ____ H2 + ____ Pb3(PO4)2
Reaction Type : ______________________________ ____ NH3+ ____ H2SO4 ____ (NH4)2SO4 Reaction Type : _____________________
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