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Chapter 2 Alkanes
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Hydrocarbons (contain only carbon and hydrogen)
Alkanes Hydrocarbons (contain only carbon and hydrogen) Saturated: (Contain only single bonds) Alkanes (CnH2N + 2 ) Cycloalkanes (CnH2N ) b) Unsaturated: contain Alkenes: double bonds (,,,CnH2N) Alkynes: triple bonds ((CnH2N - 2) Aromatic: benzene like compounds
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The structure of alkanes
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Alkyl groups
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Nomenclature of substituted alkanes
Choose the largest continuous chain Start numbering (lowest possible numbering) List substituents alphabitically. Use di, tri, tetra, penta, hexa, hepta, octa, nona, deca for identical groups Examples
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If there are two equally long continuous chains, choose the one with most branches
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Physical properties of alkanes
1) Water insoluble 2) low boiling point, which increases upon increasing the number of carbons in the alkane 3) branched alkanes have lower boiling points than the corresponding long chain alkanes
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Conformations of Alkanes:
Conformers: Stereoisomers that are interconvertible by bond rotation
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