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Hazardous Waste Management
Hazardous Waste is regulated according to the Resource Conservation and Recovery Act (RCRA) Definition The material must first be classified as a solid waste The material must then be determined to have “hazardous” properties
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Specific Definition
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Exemptions
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Specific Criteria for Hazardous Wastes
A waste my classified as Hazardous by two criteria: 1) Listing 2) Characteristic
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Listed Wastes Three Lists 1) Hazardous Waste from Non-specific Sources
Wastes from common manufacturing processes example: dirty solvents cleaning or degreasing “F” designation “F001 2) Hazardous Waste from Specific Sources Wastes from specific industrial sources example: bottom sludge from the treatment of wastewater produced by the wood preserving industry “K” designation, K048-K052 petroleum refining wastes
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3) Discarded commercial chemical products
Off-specification materials, spill residues, discarded containers That contain certain named chemical species Actually two lists a) Toxic wastes “P” designation, P076 - nitric acid b) Acutely Toxic Wastes “U” designation, U002 - acetone
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Characteristic Wastes
There are four characteristics that can Make a waste a hazardous waste
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Flashpoint < 60 C o Easily Ignited Burns Vigorously
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Aqueous solution with:
pH < 2.0 pH > 12.5 Corrodes steel at a rate Greater than 6.35 mm/yr
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Unstable and forms a toxic
fume Explodes Reacts with exposure to Air and/or water
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Bioconcentrates LD < 50 mg/kg 50 LC 50 Phytoxicity
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Where do wastes come from?
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Classification of Generators
Large Quantity Generators > 1000 kg hazardous waste generated per month Small Quantity Generators 100 – 1000 kg hazardous waste generated per month Very Small Quantity Generators < 100 kg/month
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