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Schedule Today (3/27): Continue Chapter 17

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Presentation on theme: "Schedule Today (3/27): Continue Chapter 17"— Presentation transcript:

1 Schedule Today (3/27): Continue Chapter 17
Should have read through 17.5 Friday (3/29): Continue Chapter 17 Read through 17.7 Monday (4/1): Finish Chapter 17 Wednesday (4/3): Start Chapter 11

2 Vapor Pressure of Solutions
The arrows show the net result. Why is this happening?

3 Vapor Pressure of Solutions
Note that the rate of evaporation of pure water is greater than the rate of evaporation of water from the solution. Why?

4 Vapor Pressure

5 Vaporization of Water It is not a surface phenomenon (the water vaporizes in the bubbles).

6 Vapor Pressures of Different Liquids

7 Vapor Pressure of Different Liquids
Vapor pressure increases with temperature. At what temperature is vapor pressure equal to 1 atm?

8 Vapor Pressure of Solutions
How will the vapor pressure of a solution compare to that of pure water?

9 Pure Water vs. Aqueous Solution
For a given volume of bubble, how do the pressures compare?

10 Vapor Pressure of Solutions
Vapor pressure is a colligative property (ideally depends on the concentration of particles in solution, not their identities).

11 Raoult’s Law Question Table sugar (sucrose; C12H22O11) has a solubility of 211.4g in 100.0g of water. If pure water has a vapor pressure of 23.8 torr at 25°C, determine the vapor pressure of a saturated solution of sucrose at 25°C. Table salt (NaCl) has a solubility of 36.23g in 100.0g of water. If pure water has a vapor pressure of 23.8 torr at 25°C, determine the vapor pressure of a saturated solution of NaCl at 25°C.

12 Raoult’s Law Question You have a solution of two volatile liquids, A and B (assume ideal behavior). Pure liquid A has a vapor pressure of torr and pure liquid B has a vapor pressure of torr at the temperature of the solution. The vapor at equilibrium above the solution has double the mole fraction of substance A as the solution does. What is the mole fraction of liquid A in the solution?


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