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Warm Up: “More Combined Gas Law Questions”
Today: Ideal Gas Law Learning Targets: I can use the combined gas law to calculate the effects of changing variables of gases. I can use the ideal gas law to make predictions about an ideal gas scenario. Homework: None
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More Combined Gas Law Practice
A gas occupies a volume of L. The original temperature was cooled to 7.71 ºC and the resulting volume was L. What was the original temperature of the gas? An aerosol can has a pressure of 3.2 atm of compressed difluoroethane gas. The can begins at room temperature (298K) and is chilled until the pressure reads 2.4 atm . What is the new temperature of the gas in the can? 500.0 mL of hydrogen at 20.0ºC and 121 kPa changed to STP. What is the new volume of the gas?
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The Ideal Gas Law
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Three Assumptions about Gases
assume ideal We that we live in an world where: Gases move randomly in linear paths The distance between molecules is very large (gases take up a much larger volume than the size of their atoms) Gases undergo elastic collisions – ignore any intermolecular forces that would stick gases together when they collide
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Real Gases vs. Ideal Gases
Gases are assumed to behave ideally under normal conditions The behavior of gases deviates from ideal under: HIGH pressures (gas molecules pushed closer together… more likely to feel intermolecular forces) LOW temperatures (gas molecules move very slowly and can condense into liquid if they stick together… intermolecular forces!)
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Why are these assumptions important?
PV = nRT Image source: thefreedictionary.com
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PV = nRT P V n R T The Ideal Gas Law RESSURE OLUME MOLES GAS CONSTANT
EMPERATURE Image source: popartuk.com
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The MysteRious R R is a constant that is determined from the state of gases at STP. At STP: 1 mole of a gas takes up 22.4 L PV = nRT R = PV (1 atm)(22.4L) = = atm · L nT mol · K (1 mol)(273K) Image source: toysrus .com
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Ideal Gas Law Problems PV = nRT V = nRT P V = 49.8 L V =
1.007 atm 2.05 mols of a gas are stored at 102 kPa at 25.0ºC. What is the volume this gas takes up? PV = nRT V = nRT P V = (2.05 mols)( atm · L)(298 K) (1.007 atm)(mol · K) V = 49.8 L
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Ideal Gas Law Problems PV = nRT P = nRT V P = 4.9 atm P =
1.00 moles of a gas is stored in a 5.0 L container at a temperature of 298 K. What is the pressure of the gas? PV = nRT P = nRT V P = (1.00 mols) atm· L)(298 K) (5.0 L)(mol · K) P = 4.9 atm
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Ideal Gas Law Problems PV = nRT n = PV RT 1.55 mol n =
Nitrogen gas is stored at a pressure of 523kPa in a container that is 6.3 L big at 255 K. How many grams of nitrogen are in the container? 5.16 atm PV = nRT n = PV RT 1.55 mol n = (5.16 atm)(mol · K)(6.3L) = ( atm · L)(255 K) 1.55 mol N2 28.02 g N2 x = g N2 1 mol N2
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