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AP Chemistry Zumdahl Notes, 9th ed.
A Brief Collection of notes, Chapter 2 Feel free to open these files and annotate as you feel the need…this is for your success.
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Atoms, Molecules, Ions Early History of Chemistry (read 43-44);
Fundamental Chemical Laws Antoine Lavoisier: considered the father of modern chemistry, wrote the first “modern” chemistry textbook; regarded measurement as the essential part of chemistry, arrived at law of conservation of mass…yeah! Proust: law of definite proportion: a given cpd always has the same proportion of elements by mass; led way for Dalton to come back with the concept of atoms/tiny individual particles as well as law of multiple proportions (simple whole number ratios in cpds)
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Atoms, Molecules Ions Dalton’s atomic theory
Elements made of atoms Atoms of a given element are identical; atoms of different elements are different in some fundamental way When atoms of different elements combine, a new cpd is formed, with the same makeup of atoms/elements Chemical reactions reorganize the atoms of the elements present, they do not create new elements/atoms Dalton tried making table of atomic masses; had some errors but was first idea of using table for this information Avogadro’s hypothesis: equal volumes of gases, at constant T & P, have the same # particles (1811)…resisted for half century, eventually confirmed
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Atoms, Molecules, Ions Early experiments/progress
JJ Thomson: cathode ray tubes, electrons! Millikan: mass of electron, via oil drop experiment Becquerel: radioactivity Ernest Rutherford: gold foil expt: nucleus (+), mostly empty space Think pea in football field…yeah, mostly empty space allright! Modern view of atomic structure Extremely small size, knowledge of isotopes Molecules and Ions Molecules: from covalent cpds Formula units: from ionic cpds Cations and anions
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Atoms, Molecules, Ions Periodic Table Naming simple compounds
Metals, nonmetals, metalloids Periods/rows and groups/columns/families Naming simple compounds Binary ionic cpds: name cation first, anion second (likely –ide) Type 1: ions with a single oxidation state Type 2: ions with multiple possible oxidation states Need to use –ic or –ous to distinguish (ic is higher # of two choices) Need to use Roman Numeral to indicate appropriate oxidation state Ionic cpds with polyatomic ions Essentially, same deal with larger anions (mostly; only ammonium is common cation) Binary covalent cpds: two nonmetals; think nitrogen/oxygen cpds Don’t use mono for first element
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Atoms, Molecules, Ions Acids If salt is –ate, becomes –ic
If salt is –ite, becomes –ous If per- or hypo-, these travel as well
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