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CH 14 Acids and Bases 14.1 Properties of Acids and Bases
Sour taste, change the color of acid-base indicators, some react with metals to release hydrogen gas (H2), react with bases to produce salt and water, and conduct electric current.
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Binary acid: Nomenclature Oxyacid 2 elements: H and an electronegative
Begins with hydro- Root of name of second element follows prefix Ends with -ic Oxyacid H, O, and third nonmetal
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Main acids in industry Sulfuric Acid: petroleum refining, fertilizers, production metals/paper/paint/dyes/batteries, removes water well Nitric Acid: volatile/unstable so must be dissolved in water, used in explosives, production rubber/ plastic/ dyes/ pharmaceuticals Phosphoric Acid: fertilizers and animal feed, diluted it’s used for flavoring beverages or cleaning machinery Hydrochloric Acid: in stomach for digestion, pickling metals to remove impurities, cleaning and food processing industries Acetic Acid: vinegar contains acetic acid, used synthesize chemicals, production of food supplements
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Properties of bases Taste bitter, change color of acid-base indicators, feels slippery, react with acids to produce salts and water, and conduct an electric current Arrhenious acids: increases H+ ions and Arrhenious bases: increases OH- ions Strength of acids: Strong acids: ionize completely in aq solution Weak acids: release few H+ ions in aq solution
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Aqueous solutions of bases
Metal cation with OH- anions Ionic compounds Strength of bases Depends on extent OH- ions dissociate in soln (just like acids)
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14.2 Acid-Base Theories Bronsted-Lowry Acid Bronsted-Lowry Base
Molecule/ion that is proton donor Bronsted-Lowry Base Molecule/ion that is proton acceptor Acid-base reaction -prtotons are transferred from one reactant (acid) to the other (base)
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Monoprotic Acid: acid that can only donate 1 proton (H+) per molecule
Polyprotic Acid: acid that can donate more than one proton (H+) per molecule Diprotic Acid: donate 2 protons Triprotic Acid: donate 3 protons
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Lewis Acid: atom/ion/molecule accepts e- pair to form a covalent bond
Lewis Base: atom/ion/molecule that donates an e- pair to form a covalent bond Lewis acid-base reaction: formation of one or more covalent bonds between e- pair donor and e- pair acceptor Pd 2 stopped Friday
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14.3 Acid-Base Reactions Bronsted-Lowry conjugate acid-base pairs
Conjugate base: what remains after Bronsted-Lowry acid has given up proton Conjugate acid: what is formed when Bronsted- Lowry base gains a proton Strength of conjugative acids-bases: depends on strength of acids and bases involved
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Use strengths of acids and bases to predict outcomes of reactions (pg 459)
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Amphoteric: act as either an acid or a base
Water OH- Hydroxyl group
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Neutralization Produces water and salt
Hydronium ions and hydroxide ions form water Salt is ionic compound composed of cation from base and anion from acid
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Acid precipitation Caused by industrial processes
Compounds dissolve in water Acid rain damages buildings, plants, habitats, etc.
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