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The Chemical Context of Life
Unit 2: The Chemical Context of Life
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I. Elements and Compounds
Matter – anything that takes up space and has mass Element – can’t be broken down to other substances by chemical reactions
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Compound – 2 or more elements combined in a fixed ratio
Essential elements – 20-25% of the 92 elements needed by organisms to stay healthy and reproduce Of these essential elements, 96% of living matter is carbon, hydrogen, oxygen, nitrogen. Ca, P, K, S, and few other elements account for most of the remaining 4% Trace elements are only required in minute amounts (Iodine) Compound – 2 or more elements combined in a fixed ratio
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II. Atoms and Molecules Atom – smallest unit of matter that still retains the properties of an element Nucleus contains positive protons and neutral neutrons. Negative electrons form a cloud around the nucleus.
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The neutron and proton have almost identical masses
Atomic # = # of protons (2He); also # of electrons Mass # = protons + neutrons (4He) Atomic Mass = mass of atom (in Daltons) = mass # Isotopes – atom with different # of neutrons than protons, & therefore different mass Radioactive Isotopes – nucleus decays spontaneously, giving off particles & energy.
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Chemical Bonds – sharing or transferring valence electrons, creating attractions that hold atoms together Covalent – sharing pairs of valence electrons; results in molecule Single, double, and triple bonds are covalent Valence = bonding capacity = # unpaired electrons Electronegativity = attraction for the electrons in a covalent bond
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Nonpolar C. B. = electrons of covalent bonds are equally shared by all atoms
Polar C. B. = an atom has higher electronegativity, so does not share electrons equally in covalent bonds.
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Ionic Bonds – two atoms are so unequal in electronegativity, the more electronegative atom strips an electron completely from the other; transfer of electrons Produces ions = charged atom or molecule Cations are positive ions and anions are negative ions. Ionic compounds are also called salts.
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Hydrogen Bonds – a hydrogen atom that is covalently bonded to an electromagnetic atom is attracted to another electronegative atom; H bonds are noncovalent. Van der Waals Interactions – in nonpolar covalent bonds, there can by instances when a region of an atom is slightly charged. These ever-changing “hot spots” allow atoms and molecules to stick to each other.
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III. Chemical Reactions
Energy and Reactions Energy must be added to break bonds between atoms Forms of energy used Transferred as heat Electricity, Sound, and Light are other forms of energy
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Conservation of Energy – the total energy before a reaction is equal to the total energy of the products and their surroundings. Chemical energy – energy stored within atoms and molecules that can be released when a substance reacts
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Exothermic reactions – a chemical reaction that releases energy, also called exergonic
Endothermic reactions – a chemical reaction requiring energy in order to break bonds in the reactants, also called endergonic
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IV. Balancing Chemical Reactions
Reactants vs. Products Reactants: substances before reaction Products: substances formed after reaction Ex: Na + Cl NaCl
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Conservation of Mass – matter can be neither created nor destroyed
Balancing Chemical Equations Identify the reactants and products Begin balancing one element at a time Add numbers (coefficients) in front of chemical formulas (Don’t change chemical formulas) Continue going back and forth balancing each individual element Make a final count of each individual element before going on
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