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Sigma and Pi Bonding
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Two S orbitals overlap Sigma Bond ơ
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Two px orbitals overlap
Sigma Bond
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Sigma Bonds are sausage shaped They occur when Two s orbitals overlap
Two Px orbitals overlap Head on
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As the two px orbitals overlap so do the two py orbitals if they are occupied
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Py or Pz orbital Py or Pz orbital Pi Bond
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Pi Bonds As the 2 x orbitals join [forming a sigma bond]
The y orbitals overlap [if they are occupied] They also form a modified electron cloud. Shaped vaguely like the symbol π
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Pi Bonds are shaped like the symbol Twp Py orbitals overlap
Occur when Twp Py orbitals overlap Two Pz orbitals overlap side on
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Bond Construction Single bonds are Sigma bonds
Double bonds consist of one Sigma bond and one Pi Bond Triple bonds consist of one Sigma Bond and two Pi Bonds
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