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Graham’s Law
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Diffusion and Effusion
Diffusion – the gradual mixing of 2 or more gases due to their spontaneous, random motion Effusion – molecules of gas confined in a container randomly pass through a tiny opening in the container
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The rates of diffusion and effusion depend on the velocities of the gas molecules.
Velocity is determined by the equation KE = ½mv2
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Kinetic energy is dependent on temperature, meaning two different gases will have the same kinetic energy at the same temperature ½m1v12 = ½m2v22
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Graham’s Law of Diffusion:
Rates of diffusion of gases at the same temp and pressure are inversely proportional to the square roots of their molar masses. Rate means velocity velocity = distance/time Units = m/s
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Compare the rates of diffusion of hydrogen and oxygen at the same temperature and pressure.
rateH2 √MO √32.00g/mol rateO2 √MH √2.02g/mol Hydrogen diffuses 3.98 times faster than oxygen 3.98
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Lighter gases travel faster
Heavier gases travel slower …therefore, lighter gases travel farther in the same amount of time.
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Make a kids book about gas laws!
For each Gas Law (all 8 now) - Name of law - Formula - Explain what law means (in words) - Way to remember law - Example of law (using real life examples) - Drawing
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