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ARE ALL ATOMS OF THE SAME ELEMENT IDENTICAL?
Isotopes and Average atomic mass
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Isotopes Dalton was wrong about all elements of the same type being identical Atoms of the same element can have different numbers of neutrons. Thus, different mass numbers. These are called isotopes.
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B. Isotopes Mass # Atomic #
Atoms of the same element with different mass numbers. Nuclear symbol: Mass # Atomic # Hyphen notation: carbon-12 C. Johannesson
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Naming Isotopes Using Hyphen Notation
We can also put the mass number after the name of the element: carbon-12 carbon-14 uranium-235
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Isotopes are atoms of the same element having different masses, due to varying numbers of neutrons.
Protons Electrons Neutrons Nucleus Hydrogen–1 (protium) 1 Hydrogen-2 (deuterium) Hydrogen-3 (tritium) 2
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B. Isotopes Chlorine-37 17 37 20 atomic #: mass #: # of protons:
# of electrons: # of neutrons: 17 37 20 C. Johannesson
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Isotopes Elements occur in nature as mixtures of isotopes.
Isotopes are atoms of the same element that differ in the number of neutrons.
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Atomic Mass How heavy is an atom of oxygen?
It depends, because there are different kinds of oxygen atoms. We are more concerned with the average atomic mass. This is based on the abundance (percentage) of each variety of that element in nature. We don’t use grams for this mass because the numbers would be too small.
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Measuring Atomic Mass Instead of grams, the unit we use is the Atomic Mass Unit (amu) It is defined as one-twelfth the mass of a carbon-12 atom. Carbon-12 chosen because of its isotope purity. Each isotope has its own atomic mass, thus we determine the average from percent abundance.
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D. Average Atomic Mass Avg. Atomic Mass
weighted average of all isotopes on the Periodic Table round to 2 decimal places Avg. Atomic Mass C. Johannesson
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D. Average Atomic Mass EX: Calculate the avg. atomic mass of oxygen if its abundance in nature is 99.76% 16O, % 17O, and 0.20% 18O. Avg. Atomic Mass 16.00 amu C. Johannesson
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D. Average Atomic Mass EX: Find chlorine’s average atomic mass if approximately 8 of every 10 atoms are chlorine- 35 and 2 are chlorine-37. Avg. Atomic Mass 35.40 amu C. Johannesson
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Composition of the nucleus
Atomic Masses Atomic mass is the average of all the naturally occurring isotopes of that element. Isotope Symbol Composition of the nucleus % in nature Carbon-12 12C 6 protons 6 neutrons 98.89% Carbon-13 13C 7 neutrons 1.11% Carbon-14 14C 8 neutrons <0.01% Carbon =
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