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Electrochemical Reduction of CO2 Catalyzed by Metal Nanocatalysts

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Presentation on theme: "Electrochemical Reduction of CO2 Catalyzed by Metal Nanocatalysts"— Presentation transcript:

1 Electrochemical Reduction of CO2 Catalyzed by Metal Nanocatalysts
Zhouyang Yin, G. Tayhas R. Palmore, Shouheng Sun  Trends in Chemistry  DOI: /j.trechm Copyright © 2019 Elsevier Inc. Terms and Conditions

2 Figure 1 Reaction Pathways for Electrochemical CO2 Reduction Reaction in an Aqueous Electrolyte Based on Density Functional Theory Calculations. Reaction pathways leading to the formation of formate, CO, and C–H products are highlighted. Adapted from [5]. Abbreviation: RDS, rate-determining step. Trends in Chemistry DOI: ( /j.trechm ) Copyright © 2019 Elsevier Inc. Terms and Conditions

3 Figure 2 Summary of Some Representative Nanocatalysts Based on Au (A), Ag (B), Pd (C), Sn (D), and Ni (E) for Electrochemical CO2 Reduction Reaction to CO. All potentials are versus reversible hydrogen electrode (RHE). Abbreviations: FE, Faradaic efficiency; NP, nanoparticle. Trends in Chemistry DOI: ( /j.trechm ) Copyright © 2019 Elsevier Inc. Terms and Conditions

4 Figure 3 Summary of Some Representative Nanocatalysts Based on Sn (A), Pd (B), and Ni, Bi, Co, and Mo (C) for Electrochemical CO2 Reduction Reaction to Formate. All potentials are versus reversible hydrogen electrode (RHE) unless noted otherwise. Abbreviations: FE, Faradaic efficiency; NP, nanoparticle; SCE, saturated calomel electrode. Trends in Chemistry DOI: ( /j.trechm ) Copyright © 2019 Elsevier Inc. Terms and Conditions

5 Figure 4 Summary of Tunable Cu Nanocatalyst Properties for the Electrochemical CO2 Reduction Reaction. (A) Grain boundary effects; (B) shape effects; (C) catalyst support effects; and (D) ligand effects. Abbreviations: NP, nanoparticle; RHE, reversible hydrogen electrode. Trends in Chemistry DOI: ( /j.trechm ) Copyright © 2019 Elsevier Inc. Terms and Conditions

6 Figure 5 Metal-Organic Framework (MOF) Catalysts for the Electrochemical CO2 Reduction Reaction (CO2RR). (A) A scanning electron microscopy image and structural illustration of MOF-Cu for electrochemical CO2RR, and (B) C2H4 Faradaic efficiency (FE) changes over MOF-Cu catalysts prepared under different heating conditions. Adapted from [63]. Trends in Chemistry DOI: ( /j.trechm ) Copyright © 2019 Elsevier Inc. Terms and Conditions


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