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Periodic Trends and Electron Shell Filling Model
PResentation
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7.11 Aufbau Principle and the periodic Table
As protons are added one by one to the nucleus, electrons are similarly added to the hydrogen-like orbitals Aufbau allows us to determine the electron arrangement of an atom Orbital filling diagrams tell us which orbital an electron is in when in ground state
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Hund’s Rule Tells us that the lowest energy configuration for an atom is the one that has the maximum number of unpaired electrons allowed by the Pauli rules Basically start at 1s orbital level and move on from that point Each orbital gets 1 electron first in a specific shell (S, P, D, F), and once everybody has 1 electron, we go back and give them a second buddy to fill the orbital space Represented with arrows. Upward pointing arrow indicates the first electron, downward facing arrow represents the second electron
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Periodic Table Vocabulary
1. Valence Electrons – Outermost electrons that any atom has Elements in the same group share the same valence electron number Elements in the same period share the same valence energy level 2. Transition Metals – “D block” metals. Can have multiple charges, and some produce colored solutions 3. Lanthanide/Actinide Series -- “F block elements” Pulled out sections of table
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Vocab 4. Main-Group Elements – Groups 1, 2, Basically the common elements 5. Metalloids -- On staircase, 7 elements with both metal/non-metal properties
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7.12 Periodic trends in atomic properties
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Ionization Energy Amount of energy required to remove the outermost electron from an element As an element loses a valence electron, each successive valence electron requires more energy to “take” so first ionization energy is lowest value for this measurement
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Group Trend in Ionization energy
Decreases as we move down any group on the table As elements gain energy levels and shells, the force of attraction between the nucleus and its outermost electrons is reduced So Fr would have the lowest ionization energy in group 1 And as one electron is removed the second ionization energy value increases significantly
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Period Trend in ionization energy
Across a period ionization energy increases This is because the effective nuclear charge increases as we move left to right across any period The increased number of protons in the nucleus increases the nuclear attraction for the electrons in the atom, because of this it is more difficult to remove the outermost electrons from elements across any period This is why non-metals do so well in bonding situations……they have strong nuclei
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Electronegativity trends
Similar to ionization energy trends, decreases down a group, increases across a period Trend holds true because the defining properties of the nucleus do not change Greater effective nuclear charge across a period Less of an effective nuclear charge down a group
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Atomic radius Increases down any group because of the addition of a new energy level as one moves from top to bottom Decreases across a period because of the increase in the effective nuclear charge of each atom moving left to right Once again, this explains why metals always lose electrons, and non-metals gain or at least share
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