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Chapter 6 Thermochemistry Intro Presentation
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The Nature of Energy Energy is the capacity to do work or to produce heat through a process In chemistry we are concerned with the heat transfer that occurs during chemical reactions Heat/Energy flows from high to low concentration The energy of the universe is constant (Law of Conservation of Energy)
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Law of Conservation of Energy
Energy cannot be created or destroyed, only converted from one form to another via reactions and processes Energy is classified as either kinetic or potential
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Potential Energy Energy due to position or composition
Potential energy is able to be converted to work when it is being used
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Kinetic Energy Energy due to the motion of the object
Depends on the mass of the object and its velocity Energy is able to be converted from one form (potential) to the other (kinetic) Always remember Temperature is a measurement of the randomness of a particle and is not the same thing as Heat.
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Two Ways To Transfer Energy
1. Heat– involves the transfer of energy between two objects due to a difference in temperature Does not refer to a substance that is contained by an object Moves from high to low
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Work Force acting over a distance
PE is transferred through work from one object to another So we have two ways to transfer energy, heat and work
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Energy is a State Function
A state function/property is one that depends only on the present state of the system This means it does not depend on the past/future of the object A change in the function (property) in going from one state to another is independent of the pathway taken between the two states
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Work and Heat are NOT State Functions
Energy and enthalpy are Energy changes are independent of the pathway taken because no matter what, the measured value is always the same Work and heat are dependent on the pathway that we take
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Chemical Energy 1. System– Part of the universe that we wish to focus our attention on Example: Products and reactants 2. Surroundings—Everything else in the universe Example: Container the reaction takes place in In chemistry we always take the SYSTEMS point of view
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Exothermic Process Any reaction that involves the flow of energy/heat out of the system From system to surroundings Represented by a negative sign
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Endothermic Processes
Any reaction that involves the flow of heat/energy in to the system From surroundings into system Use a positive sign to indicate that any process is endothermic
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First Law of Thermodynamics
States that the energy of the universe is constant Basically this law is the law of conservation of energy According to this law, the amount of heat lost in any process should equal the amount of heat gained by some object related to the process
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Internal Energy Sum of KE and PE equals the internal energy (E) of the system In the equation, the sign reflects the systems point of view If the system works on the surroundings w is (-) because work flows out of system If the surrounding are working on the system w is (+) because energy will flow into the system
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Colour scheme Text & Lines Background Shadows Title Text Fills Accent
Hyperlink Followed Hyperlink Text Box
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Sample Graph
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Picture slide Bullet 1 Bullet 2
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Process Flow Design Plan Build Test Evaluate Bullet 1 Bullet 2
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Example of a table Title Data
Note: PowerPoint does not allow you to have nice default tables - but you can cut and paste this one
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Examples of default styles
Text and lines are like this Hyperlinks like this Visited hyperlinks like this Table Text box Text box With shadow
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