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Published bySebastian Larsen Modified over 5 years ago
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Aim: How do entropy and enthalpy affect reactions?
Do Now: Take out a calculator and reference tables. Consider the following reaction: 2SO2(g) + O2(g) 2SO3(g) + heat Describe what can be done to shift the equilibrium to the right. What could be done to shift the equilibrium to the left?
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2SO2(g) + O2(g) 2SO3(g) + heat
Answers to the do now:
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What causes chemical and physical changes to occur in nature?
Enthalpy – The tendency in nature to change into a state of lower energy. Any reaction that occurs will occur spontaneously if it leads to increased enthalpy. Example: Exothermic reactions move to a state with lower energy. Why? Exothermic reactions release some of the energy of the reactants.
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What causes chemical and physical changes to occur in nature?
Entropy – The tendency in nature to change into a state of greater randomness or disorder. The greater the disorder, the higher the entropy. Why is higher entropy favored over less? It is necessary for particles to collide in a specific way to maintain a specific order. On the other hand, there are many ways particles can collide to produce disorder. Therefore, entropy is easier.
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Examples of entropy Physical changes – solid to liquid to gas.
Chemical changes – compounds have a greater amount of order than the free elements of which they are composed. How can we identify whether the reactants or products have more entropy? Consider the following: What kind of phase changes are occurring. Generally the side of the equation with the greater number of molecules has the greater entropy.
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Activity/Homework Activity (IN CLASS) – Answer the questions on the worksheet you were given. HW Review Book Pages Copy and answer #36-44
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