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Molar heat capacity at constant pressure for benzene from 0 to 500 K.

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Presentation on theme: "Molar heat capacity at constant pressure for benzene from 0 to 500 K."— Presentation transcript:

1 Molar heat capacity at constant pressure for benzene from 0 to 500 K.
melting point boiling point Molar heat capacity at constant pressure for benzene from 0 to 500 K. From McQuarrie & Simon “Physical Chemistry”

2 Molar enthalpy relative to H(0) for benzene from 0 to 500 K.
melting point boiling point Molar enthalpy relative to H(0) for benzene from 0 to 500 K. From McQuarrie & Simon “Physical Chemistry”

3 CHAPTER 2: FIGURE UN2C.1 PHYSICAL CHEMISTRY: THERMODYNAMICS, STRUCTURE, AND CHANGE 10E | PETER ATKINS | JULIO DE PAULA © W. H. FREEMAN AND COMPANY PHYSICAL CHEMISTRY: QUANTA, MATTER, AND CHANGE 2E| PETER ATKINS| JULIO DE PAULA | RONALD FRIEDMAN © W. H. FREEMAN D COMPANY

4 CHAPTER 2: FIGURE 2C.1 PHYSICAL CHEMISTRY: THERMODYNAMICS, STRUCTURE, AND CHANGE 10E | PETER ATKINS | JULIO DE PAULA © W. H. FREEMAN AND COMPANY PHYSICAL CHEMISTRY: QUANTA, MATTER, AND CHANGE 2E| PETER ATKINS| JULIO DE PAULA | RONALD FRIEDMAN © W. H. FREEMAN D COMPANY

5 CHAPTER 2: FIGURE 2D.10 PHYSICAL CHEMISTRY: THERMODYNAMICS, STRUCTURE, AND CHANGE 10E | PETER ATKINS | JULIO DE PAULA © W. H. FREEMAN AND COMPANY PHYSICAL CHEMISTRY: QUANTA, MATTER, AND CHANGE 2E| PETER ATKINS| JULIO DE PAULA | RONALD FRIEDMAN © W. H. FREEMAN D COMPANY

6 CHAPTER 2: FIGURE 2D.11 / bar PHYSICAL CHEMISTRY: THERMODYNAMICS, STRUCTURE, AND CHANGE 10E | PETER ATKINS | JULIO DE PAULA © W. H. FREEMAN AND COMPANY PHYSICAL CHEMISTRY: QUANTA, MATTER, AND CHANGE 2E| PETER ATKINS| JULIO DE PAULA | RONALD FRIEDMAN © W. H. FREEMAN D COMPANY

7 Formulations of the Second Law of Thermodynamics
Kelvin-Planck statement: No process is possible whose sole result is the absorption of heat from a reservoir and the conversion of this heat into work. Clausius statement: No process is possible whose sole result is the transfer of heat from a cooler to a hotter body. T1 < T2

8 CHAPTER 3: FIGURE 3A.8 PHYSICAL CHEMISTRY: THERMODYNAMICS, STRUCTURE, AND CHANGE 10E | PETER ATKINS | JULIO DE PAULA © W. H. FREEMAN AND COMPANY PHYSICAL CHEMISTRY: QUANTA, MATTER, AND CHANGE 2E| PETER ATKINS| JULIO DE PAULA | RONALD FRIEDMAN © W. H. FREEMAN D COMPANY

9 CHAPTER 3: FIGURE 3A.7 PHYSICAL CHEMISTRY: THERMODYNAMICS, STRUCTURE, AND CHANGE 10E | PETER ATKINS | JULIO DE PAULA © W. H. FREEMAN AND COMPANY PHYSICAL CHEMISTRY: QUANTA, MATTER, AND CHANGE 2E| PETER ATKINS| JULIO DE PAULA | RONALD FRIEDMAN © W. H. FREEMAN D COMPANY

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