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Nuclear physics radioactivity
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Binding Energy and Nuclear Forces
Example 41-4: Binding energy of last neutron. What is the binding energy of the last neutron in ? Solution: Add the mass of a neutron to the mass of a carbon-12 nucleus and subtract the mass of the carbon-13 nucleus. Answer: 4.95 MeV.
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Binding: Nuclear Force
So what holds the nucleus together? Coulomb force? Gravity? Coulomb force only acts on charged particles Repulsive between protons, and doesn’t affect neutrons at all. Gravitational force is much too weak. It was showed that the gravitational force is much weaker than Coulomb force.
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The Strong Nuclear Force
New force. Dramatically stronger than Coulomb force. But not noticeable at large distances. I.e. Atoms do not attract each other. Must be qualitatively different than Coulomb force. How can we characterize this force? Range is on the order of the size of nucleus. Stronger than Coulomb force at short distances.
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A strong nuclear force Electron is bound in atom by Coulomb attraction. Strength ~10 eV. Protons in nucleus are 50,000 times closer together. Coulomb repulsion ~500,000 eV = 0.5 MeV Nuclear force must be much stronger than this. Experimentally, the strong nuclear force is ~ 100 times stronger than Coulomb force Nucleons are bound in nucleus by ~ 8 MeV / nucleon (8,000,000 eV / nucleon)
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Binding Energy and Nuclear Forces
The force that binds the nucleons together is called the strong nuclear force. It is a very strong, but short-range, force. It is essentially zero if the nucleons are more than about m apart. The Coulomb force is long-range; this is why extra neutrons are needed for stability in high-Z nuclei. Nuclei that are unstable decay; many such decays are governed by another force called the weak nuclear force.
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Radioactivity Toward the end of the 19th century, Becquerel found minerals (containing uranium) would darken a photographic plate even in the absence of light. This phenomenon is now called radioactivity. Marie and Pierre Curie isolated two new elements that were highly radioactive; they are now called polonium and radium.
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Radioactivity Radioactive rays were observed to be of three types:
Alpha rays, which could barely penetrate a piece of paper Beta rays, which could penetrate 3 mm of aluminum Gamma rays, which could penetrate several centimeters of lead We now know that alpha rays are helium nuclei, beta rays are electrons, and gamma rays are electromagnetic radiation.
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Is the radiation charged?
Alpha radiation positively charged Beta radiation negatively charged Gamma radiation uncharged
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Radioactivity Alpha and beta rays are bent in opposite directions in a magnetic field, while gamma rays are not bent at all. Rutherford and others studied the rays experimentally in 1898, it was found that alpha rays ( nuclei of Helium atom) are charged positively, beta rays are charged negatively (electrons) and gamma rays are neutral ( high energy photons). Figure Alpha and beta rays are bent in opposite directions by a magnetic field, whereas gamma rays are not bent at all.
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Alpha radiation Alpha radiation now known to be a helium nucleus (2 protons, 2 neutrons) Piece of atom (alpha particle) is broken from heavy nucleus and ejected
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Alpha Decay Experiments have shown that when nuclei decay, the number of nucleons (=mass number A) is conserved as well as the electric charge. Example of alpha decay: ( when nucleus emits an alpha particle ( 𝟐 𝟒 𝑯𝒆 ), it looses two protons and two neutrons. Radium-226 will alpha decay to radon-222: Figure Radioactive decay of radium to radon with emission of an alpha particle. Radioactive decay of radium to radon with emission of an alpha particle. Parent nucleus Daughter nucleus This is called Transmutation
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A new element-example When a nucleus emits an alpha-particle, it loses two neutrons and two protons. It becomes a different element (the number of protons in the nucleus has changed). Example: 2 protons 2 neutrons Alpha particle 92 protons 146 neutrons 90 protons 144 neutrons Thorium is the element with 90 electrons (and hence 90 protons in the nucleus)
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Decay chain originates at 238U
Number of protons decay Number of neutrons
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Alpha Decay In general, alpha decay can be written:
Alpha decay occurs when the strong nuclear force cannot hold a large nucleus together. The mass of the parent nucleus is greater than the sum of the masses of the daughter nucleus and the alpha particle; this difference is called the disintegration energy.
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Alpha Decay Example 41-5: Uranium decay energy release.
Calculate the disintegration energy when (mass = u) decays to ( u) with the emission of an α particle. (As always, masses given are for neutral atoms.) Example 41-6: Kinetic energy of the α in decay. For the above decay, how much of the 5.4-MeV disintegration energy will be carried off by the α particle? Solution: Using conservation of energy gives E = u = 5.4 eV. Conservation of energy and momentum show that the α particle carries off 5.3 eV, or 98% of the disintegration energy.
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A use for alpha-decay Smoke detectors contain radioactive americium-241 (half-life 432 yrs) 241Am decays by alpha emission. Alpha particles from the americium collide with oxygen and nitrogen particles in the air creating charged ions. An electrical current is applied across the chamber in order to collect these ions (just like geiger counter!) When smoke is in chamber, smoke absorbs alpha particles. Current decreases, detected by electronics
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Beta decay Beta radiation… Now known to be an electron.
Radioactive nucleus emits an electron How can this be? There are no electrons in the nucleus! Has only neutrons and protons. Particles are not forever! Charge is forever, energy + mass is forever But particles can appear and disappear or be changed
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βeta decay There are three radioactive-decay processes in which the mass number A remains unchanged while Z and N change by ∓1; These are: β- decay, in which a neutron inside a nucleus changes into a proton with the emission of an electron; β+ decay, in which a proton inside a nucleus changes into a neutron with the emission of a positron; and electron capture (EC), in which a proton in a nucleus changes to a neutron by capturing an atomic electron, usually a 1s electron from the K shell since these have the highest probability density in the vicinity of the nucleus. Those nuclei on the neutron rich side of the energy valley will tend to decay by β- emission, while those on the proton-rich side will most probably decay by β+ emission or electron capture.
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Beta decay Nucleus emits an electron (negative charge)
Must be balanced by a positive charge appearing in the nucleus. This occurs as a neutron changing into a proton
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Beta Decay -Example Beta (β- )decay occurs when a nucleus emits an electron. An example is the decay of carbon-14: The nucleus still has 14 nucleons, but it has one more proton and one fewer neutron. This decay is an example of an interaction that proceeds via the weak nuclear force.
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Example: Radioactive carbon
14C naturally present in the atmosphere as a result of transmutation of 14N. Cosmic ray proton shatters nucleus of atmospheric gas atom. This produces neutrons. Neutron knocks proton out of 14N nucleus. 14N becomes 14C after losing neutron
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Beta Decay -Example Beta decay (β+ ) can also occur where the nucleus emits a positron rather than an electron: And a nucleus can capture one of its inner electrons (EC):
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Beta Decay The electron in beta decay is not an orbital electron; it is created in the decay within the nucleus itself. The fundamental process is a neutron decaying to a proton, electron, and neutrino ( q=0 and m=0): One neutron changes to a proton in the process and in the process (to conserve charge) emits an electron. The need for a particle such as the neutrino was discovered through analysis of energy and momentum conservation in beta decay – it could not be a two-particle decay.
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Beta Decay Neutrinos are notoriously difficult to detect, as they interact only weakly. Direct evidence for their existence was not available until in the late 1950 (Fermi). The symbol for the neutrino is the Greek letter nu (𝜈); using this, we write the beta decay of carbon-14 as: The bar sign indicate that it is an antineutrino (through β- )
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Beta Decay- Example Beta decay (β+)can also occur where the nucleus emits a positron rather than an electron: And a nucleus can capture one of its inner electrons (EC):
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In general, we can write beta decay in the following form:
And similarly for electron capture (EC):
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Beta Decay Example 41-7: Energy release in decay.
How much energy is released when decays to by β emission? Solution: The masses can be found in Appendix F; the mass difference is u, which corresponds to an energy of 156 keV.
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Gamma decay So far Both can leave the nucleus in excited state
Alpha decay: alpha particle emitted from nucleus Beta decay: electron or positron emitted Both can leave the nucleus in excited state Just like a hydrogen atom can be in an excited state Hydrogen emits photon as it drops to lower state. Nucleus also emits photon as it drops to ground state This is gamma radiation But energies much larger, so extremely high energy photons.
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Gamma Decay Gamma rays are very high-energy photons. They are emitted when a nucleus decays from an excited state to a lower state, just as photons are emitted by electrons returning to a lower state. Figure Energy-level diagram showing how 125B can decay to the ground state of 126C by β decay (total energy released = 13.4 MeV), or can instead decay to an excited state of 126C (indicated by *), which subsequently decays to its ground state by emitting a 4.4-MeV γ ray.
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Conservation of Nucleon Number and Other Conservation Laws
A new law is evident by studying radioactive decay: the total number of nucleons cannot change.
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Half-Life and Rate of Decay
Nuclear decay is a random process; the decay of any nucleus is not influenced by the decay of any other. Figure Radioactive nuclei decay one by one. Hence, the number of parent nuclei in a sample is continually decreasing. When a 146C nucleus emits the electron, the nucleus becomes a 147N nucleus. Radioactive nuclei decay one by one. Hence, the number of parent nuclei in a sample is continually decreasing. When a nucleus emits the electron, the nucleus becomes a nucleus.
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Half-Life and Rate of Decay
We can determine, on a probabilistic basis, approximately how many nuclei in a sample will decay over a given time period, by assuming that each nucleus has the same probability of decaying in each second that it exits. Therefore, the number of decays ΔN in a very short time interval Δt is proportional to the number of nuclei present and to the time: ∆𝑁=−𝜆𝑁 Δ𝑡 Here, λ is a constant characteristic of that particular nuclide, and is called the decay constant.
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Half-Life and Rate of Decay
This equation can be solved for N as a function of time: This is the radioactive decay law Figure (a) The number N of parent nuclei in a given sample of 146C decreases exponentially. (b) The number of decays per second also decreases exponentially. The half-life of 146C is about 5730 yr, which means that the number of parent nuclei, N, and the rate of decay, |dNdt|, decrease by half every 5730 yr. The number N of parent nuclei in a given sample of decreases exponentially. The number of decays per second also decreases exponentially. The half-life of is about 5730 yr, which means that the number of parent nuclei, N, and the rate of decay, |dN/dt|, decrease by half every 5730 yr.
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Activity of a sample The rate of decay in a pure sample or number of decays per second is called activity and is 𝑑𝑁 𝑑𝑡 The activity a t=0 is defined by 𝒅𝑵 𝒅𝒕 𝟎 =𝝀 𝑵 𝟎 The activity at any other time t=0 is defined by 𝑑𝑁 𝑑𝑡 = 𝑑𝑁 𝑑𝑡 0 𝑒 −𝜆𝑡
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Half-Life and Rate of Decay
The half-life is the time it takes for half the nuclei in a given sample to decay. It is related to the decay constant:
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Half-Life and Rate of Decay
Example 41-8: Sample activity. The isotope has a half-life of 5730 yr. If a sample contains 1.00 x 1022 carbon-14 nuclei, what is the activity of the sample? Solution: Find the decay constant from the half life: λ = 3.83 x s-1. Multiplying by the number of atoms in the sample gives the activity, 3.83 x 1010 decays/sec.
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Half-Life and Rate of Decay
Conceptual Example 41-9: Safety: activity versus half-life. One might think that a short half-life material is safer than a long half-life material because it will not last as long. Is this an accurate representation of the situation? No, a Shorter half time means the activity is higher and thus more “radioactive” and can cause more biological damage. On the other hand, a longer half-life for the same sample size N means a lower activity but we have to worry about it for longer and find safe storage until it reaches a safe (low) level of activity. Solution: No. A shorter half-life means the activity is higher and thus more “radioactive” and can cause more biological damage. On the other hand, a shorter half-life means the material will all decay to a low level sooner. For the same sample size N, a short half-life material is more radioactive but for a shorter time. Longer half-life materials pose the problem that they have to be safely stored for longer until they reach a safe (low) level of activity.
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Half-Life and Rate of Decay
Example 41-10: A sample of radioactive A laboratory has 1.49 μg of pure , which has a half-life of 10.0 min (600 s). (a) How many nuclei are present initially? (b) What is the activity initially? (c) What is the activity after 1.00 h? (d) After approximately how long will the activity drop to less than one per second (1 s-1)? Solution: a. Use Avogadro’s number (or equivalently, the atomic mass); there are 6.90 x 1016 nuclei. b. The decay constant is λ = 1.55 x 10-3 s-1; therefore the activity at t = 0 is 7.97 x 1013 decays/sec. c. Use equation 41-7c; the activity will be 1.25 x 1012 s-1. d. Solving Equation 41-7c for t gives t = 7.70 h.
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Radioactive Dating Radioactive dating can be done by analyzing the fraction of carbon in organic material that is carbon-14. The ratio of carbon-14 to carbon-12 in the atmosphere has been roughly constant over thousands of years. A living plant or tree will be constantly exchanging carbon with the atmosphere, and will have the same carbon ratio in its tissues.
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Radioactive Dating When the plant dies, this exchange stops. Carbon-14 has a half-life of about 5730 years; it gradually decays away and becomes a smaller and smaller fraction of the total carbon in the plant tissue. This fraction can be measured, and the age of the tissue deduced. Objects older than about 60,000 years cannot be dated this way – there is too little carbon-14 left.
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Radioactive Dating Other isotopes are useful for geologic time scale dating. Uranium-238 has a half-life of 4.5 x 109 years, and has been used to date the oldest rocks on Earth as about 4 billion years old.
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Detection of Radiation
Individual particles such as electrons, neutrons, and protons cannot be seen directly, so their existence must be inferred through measurements. Many different devices, of varying levels of sophistication, have been developed to do this.
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Detection of Radiation
The Geiger counter is a gas-filled tube with a wire in the center. The wire is at high voltage; the case is grounded. When a charged particle passes through, it ionizes the gas. The ions cascade onto the wire, producing a pulse. Figure Diagram of a Geiger counter.
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Detection of Radiation
A scintillation counter uses a scintillator – a material that emits light when a charged particle goes through it. The scintillator is made light-tight, and the light flashes are viewed with a photomultiplier tube, which has a photocathode that emits an electron when struck by a photon and then a series of amplifiers. Figure Scintillation counter with a photomultiplier tube.
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Detection of Radiation
A cloud chamber contains a supercooled gas; when a charged particle goes through, droplets form along its track. Similarly, a bubble chamber contains a superheated liquid, and it is bubbles that form. In either case, the tracks can be photographed and measured. Figure In a cloud chamber or bubble chamber, droplets or bubbles are formed around ions produced by the passage of a charged particle.
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Detection of Radiation
A wire drift chamber is somewhat similar to, but vastly more sophisticated than, a Geiger counter. Many wires are present, some at high voltage and some grounded; in addition to the presence of a signal, the time it takes the pulse to arrive at the wire is measured, allowing very precise measurement of position. Wire-drift chamber inside the Collider Detector at Fermilab (CDF) Figure Wire-drift chamber inside the Collider Detector at Fermilab (CDF)
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