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Nuclear Reactions
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Natural Transmutation
1 term on reactant side Original isotope 2 terms on product side Emitted Particle New Isotope Happens all by itself (spontaneous) Not affected by anything in environment
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Natural Transmutation
16N 0e O 7 -1 8 2 terms on product side 1 term on reactant side
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Artificial Transmutation
Cause it to happen by smashing particles into one another 2 terms on reactant side Original Isotope Particle that hits it neutron, proton, or -particle Product side: usually 2 terms
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Artificial Transmutation
27Al He 30P + 1n 15 13 2 Original isotope or target nucleus “Bullet” -what hits isotope
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Artificial Transmutation
27Al + 4He 30P + 1n All of these equations have 2 reactants! 13 2 15 14N + 4He 17O + 1H 1 2 8 7 75As + 4He 78Br + 1n 2 35 33 37Cl + 1n 38Cl 17 17
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Bombarding with Protons or
Protons and -particles have positive charge and mass do some damage when hit target nucleus must be accelerated to high speeds to overcome repulsive forces between nucleus & particle (both are +)
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What is an accelerator? vacuum chamber (usually a long pipe)
surrounded by vacuum pumps, magnets, radio- frequency cavities, high voltage instruments and electronic circuits inside the pipe particles are accelerated to very high speeds then smashed into each other
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Splitting heavy nucleus into 2 lighter nuclei
Fission Reaction Splitting heavy nucleus into 2 lighter nuclei Requires a critical mass of fissionable isotope Controlled – nuclear reactor Uncontrolled – bomb
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Fission Reactant side: 2 terms Product side: at least 2 terms
1 heavy isotope (examples: U-235 or Pu-239) Bombarding particle – usually a neutron Product side: at least 2 terms 2 medium-weight isotopes 1 or more neutrons Huge amount of energy is released Fission = Division
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Fission 235U + 1n 91Kr + 142Ba + 31n + energy 56 92 36
92 36 235U + 1n 72Zn + 160Sm + 41n + energy 62 92 30 More than 200 different product isotopes identified from fission of U-235 A small amount of mass is converted to energy according to E = mc2
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Fission Chain Reaction
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Fusion Reactant side has 2 small nuclei: Product side:
H + H; H + He; He + He Product side: 1 nucleus (still small) and maybe a particle Source of sun’s energy 2 nuclei unite 2H + 3H 4He + 1n + energy 2 1 1
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CERN 27 kilometer ring Particles travel just below speed of light
In 10 hrs: particles make 400 million revolutions of the ring
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FermiLab 4 miles in circumference!
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Balancing Nuclear Equations
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Nuclear Equations - tasks
Identify type (4 types) Balance to find 1 unknown term
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Natural Transmutation – ID
1 term on reactant side starting isotope 2 terms on product side ending isotope and emitted particle Type of particle emitted characteristic of isotope – Table N
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Nuclear Equations To balance: use conservation of both atomic number & mass number Mass number = left superscript Atomic Number = left subscript
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Balancing Nuclear Equations
16N 0e O -1 7 8 Conservation of mass number: 16 = Conservation of atomic number: 7 =
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Writing Equations Write the equation for the decay of Thorium-232
Use Table N to find the decay mode: α Write the initial equation: 232Th 4He + X 90 2 figure out what element it turned into
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What’s under the hat? Little cats X, Y, & Z!
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Write an equation for the α decay of Am-241
241 Am 4He + YX What’s X? 95 2 Z
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so Y = 228 232 = 4 + Y Conservation of Mass Number:
232Th 4He X Y Z 90 2 Conservation of Mass Number: sum of mass numbers on left side must = sum of mass numbers on right side
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so Z = 88 90 = 2 + Z Conservation of Atomic Number:
232Th 4He + 228X 90 Z 2 90 = Z so Z = 88 Conservation of Atomic Number: sum of atomic numbers on left side must = sum of atomic numbers on right side
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232Th 4He + 228X 90 2 88 Use the PT to find X: X = Ra 232Th 4He + 228Ra 90 2 88
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Alpha (α) decay: 233U 229Th + 4He 232Th 228Ra + 4He
232Th 228Ra + 4He 175Pt 171Os + 4He
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How does the mass number or atomic number change in α,β or γ decay?
go to Table N: find isotope that decays by alpha or β decay write the equation see how the mass number (or atomic number) changes 22688Ra 42 + X so X has to be 22286X X is Rn-222 mass number decreases by 4; atomic number decreases by 2
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Write an equation for the decay of Am-241
so Y = 237 241 Am 4He + YX 95 2 Z so Z = 93 95 = Z What’s X? X = Np
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Radioactive Decay Series
Sometimes 1 transmutation isn’t enough to achieve stability Some radioisotopes go through several changes before they achieve stability (and are no longer radioactive)
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β C 14N + 0e 6 7 -1 β F 18O + 0e 9 8 +1
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How does the mass number or atomic number change in or decay?
Go to Table N; find an isotope that decays by α, or , write the equation; see how the mass number (or atomic number) changes 226Ra 4 + X so X has to be 222X X is Ra-222 mass number decreases by 4 atomic number decreases by 2 88 86 2
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