1. Intermolecular Vibrational Motions of Solute Molecules Confined in the Nonpolar Domains of Ionic Liquids Edward L. Quitevis, Department of Chemistry & Biochemistry, Texas Tech University
BL – Bucaro-Litovitz function
AG – Antisymmetrized Gaussian function
[C5mim]+
[NTf2]-
At low concentrations (< 10 mol %), CS2 and IL contributions to optical Kerr effect spectra of mixtures are additive.
CS2 mainly localized in the interior of the nonpolar domains.
Intermolecular dynamics in the nonpolar domains is similar to that in alkane solvent.