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(From A. Zewail’s Nobel Lecture 1999)
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Jahn-Teller Effect If a molecule has a degenerate electronic state (E or T), a normal coordinate exists that lifts the degeneracy by lowering the symmetry of the electronic state. Example: Hexa-aqua-Cu(II) complex has D4h symmetry instead of Oh, since its ground state in Oh symmetry would be degenerate (Eg). Jahn-Teller Theorem: “A nonlinear polyatomic system in a spatially degenerate electronic state distorts spontaneously in such a way that the degeneracy is lifted and a new equilibrium structure of lower symmetry is attained.” From G. Herzberg, Molecular Spectra and Molecular Structure, Vol. III From Wikipedia Commons
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Molecular Spectra and Molecular Structure,
From G. Herzberg, Molecular Spectra and Molecular Structure, Vol. III
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Roald Hoffmann, Angew. Chem. Int. Ed. 26 (1987) 846-878
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