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Chapter 13 Section 1 Gases
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Gas model Kinetic energy- energy due to motion
Kinetic theory- tiny particles in all forms of matter are in constant motion. Gases are composed of particles that are small, hard, spheres. Gas particles are in rapid and constant random motion
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Movement Gas particles travel in straight paths that are independent of each other. Gas particles will only change direction after a collision with another object. Collisions between gas molecules are elastic- no energy is lost.
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Gas Pressure Gas pressure- the force exerted by a gas per unit of surface area of an object. It is the result of billions of simultaneous collisions of rapidly moving particles. Vacuum- empty space with no particles and no pressure. Atmospheric pressure- results from collisions of air molecules with objects.
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Atmospheric pressure Barometers- measure atmospheric pressure.
The SI unit of pressure is the pascal (Pa) One atmosphere(atm) is the pressure required to support 760mm of mercury in a barometer at sea level at 25 C So units could be pascals, kilopascals, atmospheres, mm of Hg, or torr. 1 atm = 760 mmHg= 760 torr =101.3 kPa
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Kinetic energy and temperature
When temperature rises, particles will move faster so they will have a greater kinetic energy. Kelvin temperature is directly proportional to average kinetic energy of particles.
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Chapter 13 Section 2 Liquids
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Kinetic theory Unlike gases, the particles in a liquid are attracted to each other. Vaporization- changing from a liquid to a gas. Evaporation- when vaporization occurs at the surface of a liquid that is not boiling. Vapor pressure- A force due to pressure of a gas above a liquid.
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At constant vapor pressure, the number of vapor particles condensing equals the number of liquid particles vaporizing. This is called a state of equilibrium. Evaporation and condensation are still occuring, but there is no net change. Increase in temperature increases vapor pressure. Vapor pressure is measured with a manometer.
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Boiling point The temperature at which vapor pressure of the liquid is equal to the external pressure. Boiling results when liquid is heated to a high enough temperature for the particles to turn into vapor. Normal boiling point- the boiling point of a liquid at a pressure of kPa.
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Chapter 13 Section 3 Solids
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Solids The particles of solids are packed tightly together in an organized pattern. The melting point is the temperature that a solid turns into a liquid. A crystal is a substance in which the particles are arranged in a 3-dimensional orderly pattern. Ionic solids have high melting points, molecular solids have low melting points.
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Unit cell- the smallest group of particles within a crystal that retain the geometric shape.
Allotropes- two or more molecular forms of the same element in the same state. Amorphous solid- randomly arranged Glass- transparent solid that is the result of material cooling without crystalizing. Glasses do not melt but gradually soften when heated.
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Chapter 13 Section 4 State Changes
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Changes of state Boiling- liquid to gas Melting- solid to liquid
Freezing – liquid to solid Condensation- gas to liquid Sublimation- solid to gas Desublimation- gas to solid
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Phase diagrams Phase diagrams give the conditions of temperature and pressure at which a substance exists as solid, liquid, and gas. Conditions of equilibrium between two states are indicated by a line on the diagram. Triple point- The point where all three curves meet. All three phases exist at equilibrium with each other.
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