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Intermolecular Forces
Chapter 10 Review Intermolecular Forces
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#1 Explain the difference between intermolecular and intramolecular forces. Which is stronger?
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Intramolecular **Stronger**
Hold atoms together within a molecule (chem. Bonding: ionic and covalent) Intermolecular Attractive forces between molecules Responsible for many properties of matter (ex. MP and BP)
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#2 What is a dipole? Which molecules have the strongest dipole-dipole attractions?
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A dipole occurs when two atoms in a molecule have substantially different electronegativity: One atom attracts electrons more than another, becoming more negative, while the other atom becomes more positive. The greater the electronegativity difference (polarity of the bonds), the greater the dipole-dipole attraction
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#3 This type of IMF results from the constant motions of electrons and the creation of instantaneous dipoles
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London Dispersion Forces
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#4 What is the strongest type of intermolecular force?
Name the three elements with a great enough electronegativity to form this type of bond.
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Hydrogen Bond N, O, F
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#5 Compare solids, liquids and gases in terms of : Shape Volume
Movement of particles Attraction of particles Closeness of particles
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#6 This state of matter occurs at extremely high temperatures and is made up of electrons and + ions
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Plasma
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#7 List the three part of the KMT.
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#8 This is a hypothetical gas that always fits the assumptions of the KMT
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Ideal gas
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#9 What is pressure a measure of?
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Pressure is a measure of the collisions between the molecules and the walls of the container. More collisions, more pressure
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#10 This type of collision results in no net loss/gain of energy
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Elastic collision
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#11 An increase in temperature causes speed of molecules to ______________. An increase in temperature causes pressure to ______________. An increase in the number of molecules causes pressure to ______________.
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Increase
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#12 Compare Hydrogen gas and Carbon dioxide gas: at the same temperature: Which has the highest speed? Which has the highest KE?
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Hydrogen gas is faster (it’s lighter)
Both have the same KE
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#13 The process by which a gas escapes through a tiny opening is called
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Effusion
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#14 During what two conditions (found in your notes) do real gases show the greatest deviation from ideal gases?
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Low temperature, high pressure
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#15 How does water differ from most other substances when comparing the density of its solid and liquid states?
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Solid is less dense than liquid
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#16 This phenomena is a result of the attraction of a liquid to the surface of a solid, and allows water to rise up thin tubes or fibers
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Capillary Action
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#17 When there are two or more different molecular forms of the same element in the same physical state, it is an example of an
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Allotrope Ex. Diamond and Graphite (both C)
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#18 Which would have the highest melting point/boiling point
Molecules held together by hydrogen bonds Molecules held together by London dispersion forces Molecules held together by dipole-dipole attractions
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Molecules held together by hydrogen bonds
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#19 Label each change of state as endothermic or exothermic Freezing
Melting Vaporizing Condensation Deposition Sublimation
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Freezing - exo Melting - endo Vaporizing - endo Condensation – exo Deposition - exo Sublimation - endo
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#20 When two opposing changes occur at equal rates in a closed system, the system is said to be in ____________________
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Equilibrium
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#21 Which would have a higher vapor pressure, water or alcohol?
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Alcohol
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#22 the temperature at which the equilibrium vapor pressure equals the atmospheric pressure is called the ________________
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Boiling Point
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#23 Compare atmospheric pressure and boiling point at high elevations to that at low elevations
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At higher elevations, atmospheric pressure is lower, so boiling point is lower, so it takes longer to cook food
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#24 What phase change occurs as a substance goes through line ED with increasing temperature? AD? What is the point called where all three phases are in equilibrium?
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Sublimation Melting Triple Point
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