1. Case Study- Metal Ion Exchange
From Kodanko, J. J. et al. J. Am. Chem. Soc. 127, (2005)
Metal ion exchange for Na+ in [NaFe(PIC2DET)(m-O2CTrp)3]
Addition of Fe(OTf)2 induces color change from blue to red
First-order in NaFe compound, zero-order in Fe(OTf)2
ΔH‡ = 59 (±6) kJ mol-1, ΔS‡ = -20 (±6) J mol-1 K-1
Mechanism?
Created by Christian R. Goldsmith (Auburn University, and posted on VIPEr ( January 4, 2015, Copyright Christian R. Goldsmith, This work is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike License. To view a copy of this license visit 
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