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What is an Acid?
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Ca(OH)2 Ca+2 + 2OH- (Base)
The Arrhenius Theory Svante Arrhenius, a Swedish chemist, noted that acids have hydrogen while bases have hydroxide. Thus an acid was a H+ donor while a base was a OH- donor. This was the first theory of the difference between acids and bases but was later found to be too limited. HCl H+ + Cl- (Acid) H2SO4 2H+ + SO (Acid) NaOH Na OH- (Base) Ca(OH)2 Ca OH (Base)
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A Hydrogen Ion A hydrogen ion is a hydrogen atom that has lost an electron. Thus a hydrogen ion (H+) is a single proton.
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The Bronstead-Lowry Theory
In the Bronstead-Lowry theory of acids and bases, an acid is a proton donor while a base is a proton acceptor.
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Bronstead-Lowry Acid and Base
Acids donate H+ while bases accept H+ .
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The Hydronium Ion Water easily accepts a hydrogen ion and is then called a hydronium ion. A hydrogen ion and a hydronium ion are equivalent in that free hydrogen ions do not exist in water except as hydronium ions.
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Amphiprotic Substances
An amphiprotic substance can act as either an acid or as a base. It can give or accept protons. Water is amphiprotic.
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Other Amphiprotic Substances
Note that an amphiprotic species must have H in its formula because it has to be able to give a proton as well as receive a proton
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Conjugate Acids and Bases
The conjugate acid of a substance is a species with one more proton (H+). A conjugate base of a substance is a species with one less proton (H+).
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Other Conjugate Acids and Bases
Is the CH3COO- a conjugate base or acid of CH3COOH?
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Other Conjugates Identify the acid and base and their conjugates for the forward reaction.
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Conjugate Chart When one conjugate of a pair is weak, it means that the other conjugate of the pair is strong.
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