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Advanced Chemdraw Created by S. Chantal E. Stieber, California State Polytechnic University Pomona (sestieber@cpp.edu) and posted on VIPEr (www.ionicviper.org)

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Presentation on theme: "Advanced Chemdraw Created by S. Chantal E. Stieber, California State Polytechnic University Pomona (sestieber@cpp.edu) and posted on VIPEr (www.ionicviper.org)"— Presentation transcript:

1 Advanced Chemdraw Created by S. Chantal E. Stieber, California State Polytechnic University Pomona and posted on VIPEr ( on February 11, Copyright S. Chantal E. Stieber, This work is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike 3.0 Unported License. To view a copy of this license visit

2 Advanced ChemDraw Insert image of Chemdraw user interface from page 4 of the Chemdraw 16.0 user manual. Chemdraw 16 user manual

3 Drawing Complex 3-D Structures: Target complex:
Advanced ChemDraw Drawing Complex 3-D Structures: Target complex: Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Mantell, M. A.; Kampf, J. W.; Sanford, M. Improved Synthesis of [CpRRhCl2]2 Complexes, Organometallics, 2018, DOI: /acs.organomet.8b00400

4 Drawing Complex 3-D Structures:
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Start with the ligands that you will distort:

5 Drawing Complex 3-D Structures: Select the whole ligand:
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Select the whole ligand: Distort it in 3-D

6 Drawing Complex 3-D Structures: Add shading:
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Add shading: Adjust the circle as needed:

7 Drawing Complex 3-D Structures: Copy/paste first ring
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Copy/paste first ring Flip vertically to make second ring: Remove wedges, rotate, and add shading

8 Drawing Complex 3-D Structures: Build the rest of the structure:
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Build the rest of the structure: Notice the bond is in front of the top left ring

9 Drawing Complex 3-D Structures: Highlight the bond that’s in front
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Highlight the bond that’s in front Send to back:

10 Drawing Complex 3-D Structures: Add atom names using text function
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Add atom names using text function Add R groups using bonds and text labels

11 Drawing Complex 3-D Structures: Remove chemical warnings
Advanced ChemDraw Insert image of dirhodium complex from upper right in Scheme 1 in Sanford paper DOI: /acs.organomet.8b00400 Drawing Complex 3-D Structures: Remove chemical warnings

12 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Make sure everything is lined up Target: Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881 Lardy, S. W.; Schmidt, V. A. “Intermolecular Radical Mediated Anti-Markovnikov Alkene Hydroamination Using N‐Hydroxyphthalimide,” J. Am. Chem. Soc. 2018, /jacs.8b06881

13 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Draw components first Notice the different fonts. Highlight everything and make the font consistent (Arial 10) Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

14 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Add the arrow Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

15 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Add the arrow Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

16 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Line everything up It helps to use a guideline that you will later delete Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

17 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Line everything up It helps to use a guideline that you will later delete Drag all components so they are centered on the line The blue boxes show a center point Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

18 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: See how all components are now centered around the line Move the guideline and use it to line up your labels Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

19 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Remove the guideline You can change colors and boldness of specific labels Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

20 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: You can change colors and boldness of specific labels Finally, add the highlights using a shape Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

21 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: Finally, add the highlights using a shape Send the shapes to the back by right clicking Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

22 Insert image of reaction scheme above table 1 in Schmidt paper
Advanced ChemDraw Drawing Reaction Schemes: Target: And you are finished Insert image of reaction scheme above table 1 in Schmidt paper DOI: /jacs.8b06881

23 Advanced ChemDraw Drawing Catalytic Cycles (example with 3 components): Start with a circle template

24 Advanced ChemDraw Drawing Catalytic Cycles (example with 3 components): Add your 3 components

25 Advanced ChemDraw Drawing Catalytic Cycles (example with 3 components): Draw straight arrows between 3 components

26 Drawing Catalytic Cycles (example with 3 components): Bend the arrows
Advanced ChemDraw Drawing Catalytic Cycles (example with 3 components): Bend the arrows Hold over the arrow, and click/drag the center dot Drag until the arrow is inline with the circle

27 Drawing Catalytic Cycles (example with 3 components): Bend the arrows
Advanced ChemDraw Drawing Catalytic Cycles (example with 3 components): Bend the arrows Continue with other arrows

28 Advanced ChemDraw Drawing Catalytic Cycles (example with 3 components): Remove circle template Now, the cycle can be finished by adding reagents

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