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5.6.1a Other Fuels Hydrogen Alcohol
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Other Fuels Hydrogen CH4 + H2O = 3 H2 + CO Production Method 1
Steam Reforming of Natural Gas CH4 + H2O = 3 H CO In presence of a suitable catalyst
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Other Fuels Production Method 2 Electrolysis of Water
using dilute H2SO4 as catalyst forms at cathode [negative electrode] Overall H2O = H /2 O2 Too expensive in most parts of world
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Other Fuels Production Method 3
During cat-cracking of long chain alkanes not a very important method
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Other Fuels Uses of Hydrogen Haber Process for producing ammonia
N H2 = 2 NH3 Hydrogenating vegetable oils Organic synthesis
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Other Fuels Fuel - about 10% of worlds production of hydrogen is used as fuel Environmentally friendly Water is the only product of combustion H /2 O2 = H2O Major problem it is explosive with air Difficulties with storage and transport due to this and pressure
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Challenger Click here to see Challenger
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Click button to see hydrogen car video
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Hindenburg Click here to see the Hindenburg
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Petrol versus Hydrogen
Hydrogen 1299 kJ mol-1 [Heat of combustion] Petrol 5512 kJ mol-1 [Heat of combustion] 1kg petrol kJ 1 kg hydrogen kJ [kilogram calorific value] Hydrogen gives 13.4 times more heat per kg
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Alcohol C2H5OH + 3½ O2 = 2 CO2 + 3 H2O
Can be made from waste sugar cane or any other natural sugar source e.g. sugar beet Doesn’t really add to greenhouse effect Growing plants removes C from the air and then returns it. Can add up to 20% alcohol to petrol without changing engine [Gasohol] common in South America
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Biodiesel Made from rape seed oil and used cooking fat.
Doesn’t add to greenhouse effect Plants remove C from air then return it Available now in some european countries
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